• 专利标题:   Preparing graphene and ferroferric oxide-gold composite material used e.g. for X-ray imaging, by dispersing nano ferroferric oxide in reducing agent solution, ultrasonically treating, heating and dripping chloroauric acid water solution.
  • 专利号:   CN107127351-A, WO2018201715-A1, CN107127351-B, US2019168298-A1
  • 发明人:   HUANG G, LI M, YANG B, XIN M, YIN Z, ZHANG S, LI S, ZHAI W, WANG Z, LI P
  • 专利权人:   GUANGZHOU SPECIAL PRESSURE EQUIP INSPECT, GUANGZHOU SPECIAL PRESSURE EQUIP INSPECT, GUANGZHOU SPECIAL PRESSURE EQUIP INSPECT
  • 国际专利分类:   B22F001/02, B22F009/24, B22F001/00
  • 专利详细信息:   CN107127351-A 05 Sep 2017 B22F-009/24 201772 Pages: 9 Chinese
  • 申请详细信息:   CN107127351-A CN10304567 03 May 2017
  • 优先权号:   CN10304567

▎ 摘  要

NOVELTY - A graphene and ferroferric oxide-gold composite material is prepared by dispersing nano ferroferric oxide in reducing agent solution, ultrasonically treating, heating, dripping chloroauric acid water solution, stirring and curing, adding with and azide in first solvent, stirring and reacting, repeatedly washing with second solvent to obtain azide modified ferroferric oxide-gold complex, placing graphene oxide in activator, adding propargyl alcohol, continuously reacting, dissolving with azide modified ferroferric oxide-gold complex in third solvent, adding catalyst, stirring and reacting. USE - Method for preparing graphene and ferroferric oxide-gold composite material used for nuclear magnetic imaging, microwave thermoacoustic imaging, photoacoustic imaging and X-ray imaging (claimed). ADVANTAGE - The material has magnetic and good microwave absorbing performance, good plasma resonance absorption and X-ray attenuation characteristics, and makes system stable by connecting covalent bond. DETAILED DESCRIPTION - A graphene and ferroferric oxide-gold composite material is prepared by dispersing nano ferroferric oxide in reducing agent solution, ultrasonically treating, heating to 65-75 degrees C, dripping chloroauric acid water solution under stirring condition, stirring and curing to obtain ferroferric oxide core-shell structure metal compound, adding with and azide in first solvent, stirring and reacting at 40-45 degrees C, repeatedly washing with second solvent under protective atmosphere to obtain azide modified ferroferric oxide-gold complex, placing graphene oxide in activator at 65-75 degrees C, adding propargyl alcohol, continuously reacting for 20-28 hours to obtain alkylated graphene oxide, dissolving azide modified ferroferric oxide-gold complex and alkylated graphene oxide in third solvent, adding catalyst, stirring and reacting under protection atmosphere, and collecting.