• 专利标题:   Preparation of gas-sensitive material involves adding zinc nitrate hexahydrate and copper nitrate trihydrate, stirring, mixing reduced graphene oxide colloidal solution with copper-zinc precursor solution, washing, drying and annealing.
  • 专利号:   CN111017986-A
  • 发明人:   ZHAO W, XU Y, ZHANG X, LIU H, MING A, WEI F
  • 专利权人:   GRINM ENG TECHNOLOGY RES INST CO LTD
  • 国际专利分类:   C01B032/184, C01G003/02, C01G009/02, G01N027/12
  • 专利详细信息:   CN111017986-A 17 Apr 2020 C01G-003/02 202039 Pages: 9 Chinese
  • 申请详细信息:   CN111017986-A CN11345065 24 Dec 2019
  • 优先权号:   CN11345065

▎ 摘  要

NOVELTY - Preparation of gas-sensitive material involves adding zinc nitrate hexahydrate and copper nitrate trihydrate to deionized water, dispersing ultrasonically to obtain copper-zinc precursor solution, adding urea to copper-zinc precursor solution, stirring, dispersing ultrasonically to obtain reduced graphene oxide colloidal solution, mixing reduced graphene oxide colloidal solution with obtained copper-zinc precursor solution, stirring to obtain suspension liquid mixture, transferring to PTFE-lined high-pressure reaction kettle, feeding the kettle into electric furnace for reaction, completing reaction to obtain blue-gray precipitated product, reducing graphene oxide-zinc copper hydroxide carbonate complex, cooling, centrifuging, washing, drying to obtain blue-gray powder of precursor of reduced graphene oxide-zinc-copper hydroxide carbonate composite, feeding blue-gray powder in muffle furnace, and annealing blue-gray powder in air atmosphere. USE - Preparation of gas-sensitive material. ADVANTAGE - The method is simple, easy to implement, and has excellent low temperature response performance material, and overcomes the technical problem of poor zinc oxide-based material to acetone gas and does not respond at low temperatures of 150 degrees C and below. DETAILED DESCRIPTION - Preparation of gas-sensitive material involves adding (1-3):2 mass ratio of zinc nitrate hexahydrate and copper nitrate trihydrate to deionized water, dispersing ultrasonically for 5-60 minutes to obtain copper-zinc precursor solution, adding urea to copper-zinc precursor solution, stirring at room temperature for 20-120 minutes, dispersing reduced graphene oxide in deionized water, dispersing ultrasonically to obtain reduced graphene oxide colloidal solution, mixing reduced graphene oxide colloidal solution with obtained copper-zinc precursor solution, stirring magnetically to obtain suspension liquid mixture, transferring suspension mixture to PTFE-lined high-pressure reaction kettle, feeding the reaction kettle into electric furnace for reaction temperature at 90-120 degrees C for 10-18 hours, completing reaction to obtain blue-gray precipitated product, reducing graphene oxide-zinc copper hydroxide carbonate complex, cooling reduced graphene oxide-zinc-copper hydroxide carbonate composite to room temperature, centrifuging, washing, drying at 45-85 degrees C for 12-24 hours to obtain blue-gray powder of precursor of reduced graphene oxide-zinc-copper hydroxide carbonate composite, feeding blue-gray powder in muffle furnace at 400-550 degrees C for heating rate of 2-5 degrees C/minute, and annealing for 2-4 hours blue-gray powder in air atmosphere.