• 专利标题:   Graphene loaded polyvinylpyrrolidone stabilized nano ruthenium catalyst used for production of hydrogen from sodium borohydride and amine-borane, comprises polyvinylpyrrolidone stabilized nano ruthenium catalyst and graphene.
  • 专利号:   CN104888853-A, CN104888853-B
  • 发明人:   LI B, LI S, LI X, LIU S, LIU Z, SUN H, ZHANG J, FAN J, PENG Z
  • 专利权人:   HENAN CONSTR SCI RES ACAD CO LTD, UNIV ZHENGZHOU, UNIV ZHENGZHOU NORMAL, ZHENGZHOU TIANCHANG CHEM TECHNOLOGY CO, UNIV ZHENGZHOU NORMAL, HENAN PROVINCIAL ACAD BUILDING RES, ZHENGZHOU TIANCHANG CHEM TECHNOLOGY CO
  • 国际专利分类:   B01J031/06, C01B003/04
  • 专利详细信息:   CN104888853-A 09 Sep 2015 B01J-031/06 201578 Pages: 10 Chinese
  • 申请详细信息:   CN104888853-A CN10181817 17 Apr 2015
  • 优先权号:   CN10181817

▎ 摘  要

NOVELTY - Graphene loaded polyvinylpyrrolidone (PVP) stabilized nano ruthenium catalyst comprises PVP stabilized nano ruthenium catalyst as active component and carrier comprising graphene in weight ratio of 1-50:1. The PVP stabilized nano ruthenium catalyst and carrier are self-assembled by physical and chemical adsorption methods. USE - Graphene loaded PVP stabilized nano ruthenium catalyst used for production of hydrogen from sodium borohydride and amine-borane (all claimed). ADVANTAGE - The graphene loaded PVP stabilized nano ruthenium catalyst has excellent thermal stability and reusability. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) preparation of graphene loaded PVP stabilized nano ruthenium catalyst, which involves dispersing PVP stabilized nano ruthenium catalyst and graphene in a water bath, stirring at 60-100 degrees C and 200-600 rpm, leaving still for 1-10 hours, and adsorbing PVP stabilized nano ruthenium catalyst on graphene using chemical or physical adsorption method; and (2) production of hydrogen from sodium borohydride or amine-borane, using the catalyst in a mass ratio of 1-50:1.