• 专利标题:   Material used for sensor for sensing gas including toxic gas and volatile organic compound, e.g. nitrogen-based compound, alcohol, ketone, aldehyde or thiol compound, preferably acetone, ammonia, formaldehyde or methyl mercaptan, comprises polypyrrole derivative and carbon material.
  • 专利号:   WO2021172825-A1, JP2021152528-A, KR2022147100-A
  • 发明人:   KANG S, TAKADA M, KIM J, HWANG B, HWANG P Y, KIM J Y, KANG S M
  • 专利权人:   LG ELECTRONICS INC, UNIV KOOKMIN IND ACAD COOP FOUND, LG JAPAN LAB INC, UNIV KOOKMIN IND ACAD COOP FOUND, LG ELECTRONICS INC
  • 国际专利分类:   C01B032/168, C08G061/12, C08G083/00, G01N033/00, G01N027/12, C08K003/04, C08L065/00
  • 专利详细信息:   WO2021172825-A1 02 Sep 2021 C08G-083/00 202180 Pages: 48
  • 申请详细信息:   WO2021172825-A1 WOKR002176 22 Feb 2021
  • 优先权号:   JP030315, JP014314, KR732108

▎ 摘  要

NOVELTY - A gas sensing material comprises a polypyrrole derivative (I), and a carbon material. USE - Material is used for sensor for sensing gas including toxic gas and volatile organic compound, e.g. nitrogen-based compound, alcohol, ketone, aldehyde or thiol compound, preferably acetone, ammonia, formaldehyde or methyl mercaptan (all claimed). Uses include but are not limited to production environment, living environment (indoor environment), medical and health environments, pollution control application, drug application, or storage environment of home appliance (refrigerator/air purifier). ADVANTAGE - The material has excellent flexibility, and can be manufactured by simple and economical method, and enables detection of gas at a temperature of 50 degrees C to 100 degrees C, a relative humidity of 10-100% and a pressure of 1 atm, with high sensitivity and selectivity. DETAILED DESCRIPTION - A gas sensing material comprises a polypyrrole derivative of formula (I), and a carbon material. A' = 1-10C alkyl or phenyl; B' = H, halo, or group derived from halogen compound; S' = sulfur atom, nitrogen atom, oxygen atom, or group derived from polar compound containing these atoms;and n = 100-100000. INDEPENDENT CLAIMS are included for the following: (1) gas sensor, which comprises an anode, a cathode, and the gas sensing material; and (2) manufacture of the gas sensing material, which involves (i) preparing a conjugated polymer monomer, carbon material, a transition metal salt catalyst, an emulsifier and/or a dispersing agent, and a functional organic material, (ii) mixing the carbon material, transition metal salt catalyst and emulsifier and/or dispersing agent, (iii) adding conjugated polymer monomer and functional organic material to the obtained dispersion, and performing emulsion polymerization, and (iv) purifying and separating the polymerization product.