• 专利标题:   Preparing carbon-coated lithium manganate involves acid leaching pyrolusite, mixing formed manganese dioxide crystal with sulfur dioxide and solvent, mixing formed bivalent manganese with potassium permanganate, oxidizing, mixing formed manganese dioxide with lithium and carbon sources, calcining.
  • 专利号:   CN115498157-A
  • 发明人:   MA Y, HE Z, CAI B
  • 专利权人:   ANHUI BOSHI HITECH NEW MATERIAL CO LTD
  • 国际专利分类:   C01B032/05, C01G045/12, H01M004/36, H01M004/505, H01M004/62
  • 专利详细信息:   CN115498157-A 20 Dec 2022 H01M-004/36 202315 Chinese
  • 申请详细信息:   CN115498157-A CN11180684 27 Sep 2022
  • 优先权号:   CN11180684

▎ 摘  要

NOVELTY - Preparation of carbon-coated lithium manganate, by using soft manganese ore, involves: 1) subjecting pyrolusite to acid leaching, to form manganese dioxide coarse crystal, the mol concentration of acid used, is 0.5 - 6mol/l; 2) mixing manganese dioxide coarse crystals with sulphur dioxide and solvent, carrying out reduction reaction to form bivalent manganese solution; 3) mixing the bivalent manganese solution with potassium permanganate, performing oxidation reaction to form manganese dioxide; and 4) mixing manganese dioxide with lithium source and carbon source, then calcining. USE - Method is used for preparing carbon-coated lithium manganate used in lithium batteries. ADVANTAGE - The method involves using conventional non-toxic substances as raw materials which are environmentally safe. The preparation method is a simple and easy to operate process enabling easy industrialized production.