• 专利标题:   Cathode for lithium secondary battery comprises cathode active material and bottom-up graphene oxides (BGOs) coated on surface of cathode active material, where BGOs are crosslinked to each other through hydrocarbon compound containing cationic functional group.
  • 专利号:   WO2022035173-A1, KR2022019912-A, CN114556630-A, EP4027409-A1, US2022384782-A1, JP2023505050-W
  • 发明人:   KIM S, LEE J, CHOI S, SOHN K, JEONG D, SHIN H, LEE J C, CHOI S I, JUNG D, SHIN H S, SUN Q, JIN X
  • 专利权人:   LG ENERGY SOLUTION LTD, UNIV SEOUL NAT R DB FOUND, SNU R DB FOUND, LG ENERGY SOLUTION LTD, UNIV SEOUL NAT R DB FOUND, UNIV SEOUL NAT R DB FOUND, LG ENERGY SOLUTION LTD
  • 国际专利分类:   C01B032/198, H01M010/052, H01M004/02, H01M004/36, H01M004/38, H01M004/62, H01M010/0525, H01M004/587
  • 专利详细信息:   WO2022035173-A1 17 Feb 2022 202219 Pages: 30
  • 申请详细信息:   WO2022035173-A1 WOKR010542 10 Aug 2021
  • 优先权号:   KR100196, CN80005887

▎ 摘  要

NOVELTY - Cathode for a lithium secondary battery comprises a cathode active material and bottom-up graphene oxides (BGOs) coated on the surface of the cathode active material, where the BGOs are crosslinked to each other through a hydrocarbon compound containing a cationic functional group. USE - As cathode for a lithium secondary battery. ADVANTAGE - The cathode prevents the elution of lithium polysulfide and improves battery performance. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a method of manufacturing the cathode for the lithium secondary battery involving (a) manufacturing a BGO through the top method (Bottom-up approach), (b) reforming the surface of the prepared BGO with the hydrocarbon group comprising nitrogen, oxygen and sulfur, (c) preparing a mixed solution by dissolving two or more halogen-substituted hydrocarbon compounds in a solvent, and adding the surface-modified bottom-up graphene oxide (SBGO), and (d) reacting the prepared mixture to form a crosslinkage between the SBGO, and at the same time form a crosslinked surface-modified bottom-up graphene oxide (CSBGO) with each other coating the cathode active material to obtain the product; and (2) the lithium secondary battery comprising the cathode for the lithium secondary battery, a lithium metal negative electrode, an electrolyte interposed between the positive electrode and the negative electrode and a separator.