• 专利标题:   Preparing high dispersion metal or metal oxide doped adsorbent comprises using porous metal oxide or two-dimensional material as carrier, loading metal organic polyhedron, and performing reduction or oxidation reaction.
  • 专利号:   CN112844317-A, CN112844317-B
  • 发明人:   SUN L, GU M, LIU X, LI Y
  • 专利权人:   UNIV NANJING TECHNOLOGY
  • 国际专利分类:   B01J020/22, B01J020/30, C01B032/40, C07C011/04, C07C011/06, C07C007/12, C10G025/00
  • 专利详细信息:   CN112844317-A 28 May 2021 B01J-020/22 202153 Pages: 14 Chinese
  • 申请详细信息:   CN112844317-A CN11554468 24 Dec 2020
  • 优先权号:   CN11554468

▎ 摘  要

NOVELTY - Preparing high dispersion metal or metal oxide doped adsorbent comprises using porous metal oxide or two-dimensional material as carrier, loading metal organic polyhedron, preparing high dispersion metal or metal oxide doped adsorbent by reduction or oxidation reaction, where the metal or metal oxide comprising palladium, rhodium, copper, zirconium or zinc, and the content of metal or metal oxide is 0.1-6 mmol/g. USE - The method is useful for preparing high dispersion metal or metal oxide doped adsorbent. ADVANTAGE - The method: is simple; can limit the metal node number in the metal organic polyhedron; improves the dispersion degree of the metal or metal oxide; enhances the complexing ability of the active site; and improves the adsorption separation performance. DETAILED DESCRIPTION - INDEPENDENT CLAIMs are also included for: (1) high dispersion metal or metal oxide doped adsorbent comprising a metal or metal oxide loaded on a carrier, where the carrier is a porous metal oxide or a two-dimensional material, the metal or metal oxide comprising palladium, rhodium, copper, zirconium or zinc, and the content of metal or metal oxide is 0.1-6 mmol/g; (2) use of high dispersion metal or metal oxide doped adsorbent in gasoline desulfurization comprising maintaining the temperature at 20-50 degrees C, at a pressure of 0.1-0.5 MPa, and contacting, where the gasoline comprising thiophene, benzothiophene, 2-methyl-benzothiophene and/or 4, 6-dimethyl-benzothiophene sulfide gasoline; (3) use of highly dispersed metal or metal oxide doped adsorbent in separating olefin and alkane comprising maintaining the temperature at 0-70 degrees C, pressure of 0-30 MPa, and contacting, where the olefin comprising ethylene, propylene and/or butylene, and the alkane comprising methane, ethane, propane and/or butane; and (4) use of high dispersion metal or metal oxide doped adsorbent in the adsorption of carbon monoxide comprising maintaining the temperature at 0-70 degrees C, pressure of 0-30 MPa, and contacting the adsorbent and carbon monoxide mixed gas, where the carbon monoxide mixed gas comprising carbon monoxide and carbon dioxide, nitrogen, oxygen, methane, hydrogen, nitric oxide, nitrogen dioxide, ethane, propane and/or butane.