• 专利标题:   Preparing iron-manganese phosphate complex precursor used as anode active material in preparing lithium secondary battery, comprises mixing raw materials and treatment solution comprising iron, manganese and phosphorus source, and performing hydrothermal treatment, and rotary evaporation treatment.
  • 专利号:   CN115583642-A
  • 发明人:   ZHANG A, FENG G, LI H
  • 专利权人:   XIAN HESHENG HUILI NEW MATERIAL CO LTD
  • 国际专利分类:   C01B025/45, C01B032/05, H01M010/0525, H01M004/58, H01M004/62
  • 专利详细信息:   CN115583642-A 10 Jan 2023 C01B-025/45 202315 Chinese
  • 申请详细信息:   CN115583642-A CN11306490 25 Oct 2022
  • 优先权号:   CN11306490

▎ 摘  要

NOVELTY - Preparing iron-manganese phosphate complex (FexMnyDz)3(PO4)2precursor, comprises mixing the raw materials and the treatment solution comprising iron source, manganese source, D source and phosphorus source, performing hydrothermal treatment, and subjecting the hydrothermal reaction system to rotary evaporation treatment to obtain precursor, where D is other transition metal elements, and x+y+z=1, and z is 0-0.1, the treatment liquid is a mixed solution comprising water, polyethylene glycol and additive, the additive is oleic acid, oleate, citric acid, or citrate, the temperature in the rotary steaming treatment stage is 60-80℃, the rotation speed is 300-650 revolutions/minute, and the evaporation pressure is 25-50 mmHg. USE - The lithium iron manganese phosphate-carbon is used as an anode active material for the preparation of a lithium secondary battery preferably lithium-ion battery (all claimed). ADVANTAGE - The method provides (FexMnyDz)3 (PO4)2 precursor with high performance, good for subsequent preparation to obtain the active material with high electrochemical performance of the prepared material. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: preparation method of lithium iron manganese phosphate-carbon (LiFexMnyDzPO4-C); and LiFeMnDPO-C.xyz4