• 专利标题:   Preparing polymer-graphene composites, involves homogenizing initial mixture containing graphite, a polymer and a fluid medium, by shear mixing, concentrating the homogenized mixture, and blending powder with an additional polymer.
  • 专利号:   WO2018189670-A1, IN201721013041-A
  • 发明人:   RAJE V P, KUMAR A K R, SARODE R, VEEDU S, SUBRAMANIAN R
  • 专利权人:   RELIANCE IND LTD, RELIANCE IND LTD
  • 国际专利分类:   C08F114/06, C08F002/02, C08K009/04, C12Q001/00, C12N001/00, C12P001/00
  • 专利详细信息:   WO2018189670-A1 18 Oct 2018 C08F-114/06 201872 Pages: 20 English
  • 申请详细信息:   WO2018189670-A1 WOIB052494 10 Apr 2018
  • 优先权号:   IN21013041, WOIB052494

▎ 摘  要

NOVELTY - Polymer-graphene composites are prepared by: (a) forming an initial mixture containing graphite, a polymer and a fluid medium, where the ratio of the graphite to the polymer is 1:10-10:1, preferably the ratio is 1:3-3:1, and where the polymer is partially soluble in the fluid medium; (b) homogenizing the mixture obtained in step (a) by shear mixing at a shear rate of a greater than or equal to 105/s to form homogenized mixture comprising polymer particles and exfoliated graphene; (c) concentrating the homogenized mixture at a pre-determined temperature in a controlled manner to remove the fluid medium and obtain powder containing polymer particles-exfoliated graphene masterbatch/concentrate; and (d) blending the powder with an additional polymer to form polymer-graphene composites. USE - The processes are useful for preparing polymer-graphene composites, and polyvinyl chloride-graphene composites (all claimed) used in commercial applications. ADVANTAGE - The process is a fast/rapid, simple, and cost-effective way to achieve a polymer composite with good mechanical properties in polymers at a low cost. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparing polyvinyl chloride-graphene composites which involves: (a) forming an initial mixture containing graphite, polyvinyl chloride and fluid medium, where the ratio of graphite to polyvinyl chloride is 1:3-3:1, and where the polyvinyl chloride is partially soluble in the fluid medium; (b) homogenizing the mixture obtained in step (a) by shear mixing at a shear rate of greater than or equal to 105/s to obtain a homogenized mixture; (c) concentrating the homogenized mixture at 70-80 degrees C at a rotation speed of 5000-10000 revolutions per minute (RPM) to remove the fluid medium to obtain powder containing polyvinyl chloride-exfoliated graphene masterbatch/concentrate; and (d) blending the powder with an additional polyvinyl chloride to form a polyvinyl chloride-graphene composite, where the ratio of the powder to the additional polyvinyl chloride is 1:5-1:20.