• 专利标题:   Preparing counter electrode of dye sensitized solar cell, useful for transferring electrons generated by thin film to electrolyte comprises preparing water or organic graphene, placing graphene on surface of glass substrate and reducing it.
  • 专利号:   CN101976608-A, CN101976608-B
  • 发明人:   YANG Z
  • 专利权人:   IRICO GROUP CO LTD
  • 国际专利分类:   C03C017/22, H01G009/042, H01G009/20, H01L051/48, H01M014/00
  • 专利详细信息:   CN101976608-A 16 Feb 2011 H01G-009/042 201128 Pages: 8 Chinese
  • 申请详细信息:   CN101976608-A CN10293812 27 Sep 2010
  • 优先权号:   CN10293812

▎ 摘  要

NOVELTY - Preparing counter electrode of a dye sensitized solar cell comprises (i) carrying out chemical oxidization of graphite to obtain water soluble single-layer or multi-layer graphene, dissolving graphene in water, and treating under ultrasonic waves, or preparing an organic soluble grapheme and dissolving single-layer or multi-layer graphene in organic solvent, (ii) placing water soluble graphene or the organic soluble graphene on the surface of a glass substrate, and (iii) reducing the glass substrate with the single-layer or multi-layer graphene thin film by a reducing agent. USE - The method is useful for transferring electrons generated by a dye sensitized titanium dioxide thin film to an electrolyte. ADVANTAGE - The method has improved efficiency of photoelectric conversion. DETAILED DESCRIPTION - Preparing counter electrode of a dye sensitized solar cell comprises (i) carrying out chemical oxidization of graphite to obtain water soluble single-layer or multi-layer grapheme, dissolving single-layer or multi-layer graphene in water, and treating under ultrasonic waves to dissolve completely, where the concentration of the graphene solution is between 0.1 and 10 mg/ml, or preparing an organic soluble grapheme from graphite by organic functionalization of graphite, dissolving single-layer or multi-layer graphene in organic solvent, and treating under ultrasonic waves to dissolve completely, where the concentration of the graphene solution is between 0.1 and 10 mg/ml, (ii) placing water soluble graphene or the organic soluble graphene on the surface of a glass substrate and allowing to stand at a normal temperature for 12-72 hours, and drying in air to obtain single-layer or multi-layer graphene thin film, and (iii) reducing the glass substrate with the single-layer or multi-layer graphene thin film by a reducing agent for 24 hours, or roasting in the presence of nitrogen or argon gas atmosphere at 400-600 degrees C for 2-4 hours to obtain counter electrode of a dye sensitized solar cell with the glass substrate coated with single-layer or multi-layer graphene based thin film.