• 专利标题:   Preparation of conductive hydrogel with multiple shape memory and high toughness used for e.g. flexible sensors, involves mixing carboxymethyl cellulose with polymer, mixing with polyvinyl alcohol, adding conductive substances, adding ammonium persulfate, molding, heating, freezing and thawing.
  • 专利号:   CN115160596-A
  • 发明人:   GAO W, LIANG J, XIN Y
  • 专利权人:   UNIV WUYI
  • 国际专利分类:   C08J003/075, C08K003/04, C08K003/14, C08L001/28, C08L029/04, C08L005/08
  • 专利详细信息:   CN115160596-A 11 Oct 2022 C08J-003/075 202200 Chinese
  • 申请详细信息:   CN115160596-A CN10770794 30 Jun 2022
  • 优先权号:   CN10770794

▎ 摘  要

NOVELTY - Preparation of conductive hydrogel with multiple shape memory and high toughness involves mixing dialdehyde carboxymethyl cellulose as a cross-linking agent with a positively charged amino-rich polymer, mixing with polyvinyl alcohol (PVA), adding conductive substances, adding thermal initiator ammonium persulfate (APS) into the mixed solution, injecting into a glass mold, heating at 50℃ for 10 hours, freezing and thawing. USE - Preparation of conductive hydrogel with multiple shape memory and high toughness used for flexible sensors, human motion monitoring and handwriting recognition and bionics (all claimed). ADVANTAGE - The method provides conductive hydrogel with multiple shape memory, high toughness, high sensitivity, excellent self-repairing performance, reversible pH responsiveness, and temperature response, and no conflict between pH and metal ions, forms dynamic imine bond with amino-rich polymer. The MXene and graphene oxide as conductive filler can provide excellent conductive stability. The obtained hydrogel has improved mechanical property.