• 专利标题:   Gas separation membrane for use in composite filter membranes for carbon dioxide capture, comprises porous support which is deposited nanoporous single-layer graphene film with carbon dioxide-philic polymer film.
  • 专利号:   EP3593893-A1, WO2020011892-A1
  • 发明人:   AGRAWAL K V, HE G
  • 专利权人:   ECOLE POLYTECHNIQUE FEDERALE LAUSANNE, ECOLE POLYTECHNIQUE FEDERALE LAUSANNE
  • 国际专利分类:   B01D053/22, B01D067/00, B01D069/12, B01D071/02
  • 专利详细信息:   EP3593893-A1 15 Jan 2020 B01D-053/22 202008 Pages: 15 English
  • 申请详细信息:   EP3593893-A1 EP182624 10 Jul 2018
  • 优先权号:   EP182624

▎ 摘  要

NOVELTY - A gas separation membrane comprises porous support which is deposited a nanoporous single-layer graphene film with a carbon dioxide-philic polymer film having a thickness of 5-100 nm coated on top of graphene nanopores, acting as a carbon dioxide-selective film, where the carbon dioxide-philic polymer is swollen with another low molecular-weight carbon dioxide-philic polymer. USE - Gas separation membrane for use in composite filter membranes for carbon dioxide capture. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a method for manufacturing gas separation membrane, which involves synthesizing monolayer graphene on a copper foil, incorporating nanopores in the graphene lattice, functionalizing the graphene surface with oxidative groups, coating graphene with a carbon dioxide-philic polymer layer, coating the resulting film in with poly(1-trimethylsilyl-1-propyne) to improve the mechanical strength of the film allowing crack-free transfer, removing copper by chemical etching, swelling the carbon dioxide-philic polymer layer with a low molecular-weight carbon dioxide-philic polymer, and transferring the resulting film onto a porous support.