• 专利标题:   Cobalt and aluminum molybdenum disulfide doped reduced graphene oxide aerogel useful for electrochemically extracting uranium from seawater, comprises cobalt-aluminum-doped molybdenum disulfide powder and graphene oxide dispersion liquid as raw materials.
  • 专利号:   CN115090226-A, CN115090226-B
  • 发明人:   LI Y, QIN W, WANG Q, JIAN J, WU X
  • 专利权人:   HARBIN INST TECHNOLOGY
  • 国际专利分类:   B01J013/00, B01J020/02, B01J020/20, B01J020/28, B01J020/30, C02F101/20, C02F103/08
  • 专利详细信息:   CN115090226-A 23 Sep 2022 B01J-013/00 202203 Chinese
  • 申请详细信息:   CN115090226-A CN10568031 24 May 2022
  • 优先权号:   CN10568031

▎ 摘  要

NOVELTY - Cobalt and aluminum molybdenum disulfide doped reduced graphene oxide aerogel comprises cobalt-aluminum-doped molybdenum disulfide powder and graphene oxide dispersion liquid as raw materials, the mass ratio of graphene oxide and cobalt-aluminum-doped molybdenum disulfide powder is (30:70) to (70:30), prepared by hydrothermal process; cobalt-aluminum-doped molybdenum disulfide powder is prepared by mechanical alloying process with aluminum powder, cobalt powder and molybdenum disulfide powder as raw materials, phase of molybdenum disulfide is 1T phase; in the cobalt-aluminum-doped molybdenum disulfide powder, doping amount of aluminum is 1-5 wt.%, and doping amount of cobalt is 1-20 wt.%. USE - The aerogel is useful for electrochemically extracting uranium from seawater. ADVANTAGE - The aerogel: is material with high hydrogen evolution performance and specific adsorption capacity for uranyl ions, by applying electrochemical methods to seawater to extract uranium, a higher seawater uranium extraction capacity is achieved, and shows excellent uranium extraction performance. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: Preparing the cobalt and aluminum molybdenum disulfide doped reduced graphene oxide aerogel comprising mixing cobalt-aluminum-doped molybdenum disulfide powder with graphene oxide dispersion, carrying ultrasonic treatment, placing in a reaction kettle, carrying hydrothermal reaction, after the reaction, cooling to room temperature, and freeze-drying. Electrochemically extracting uranium from seawater comprising filtering the uranium-containing seawater, adding it to the electrolytic cell, placing a three-electrode system, and electrolyzing at a voltage of -0.6V to -1.6V for 0.2-2 hours; where, silver/silver chloride electrode as the reference electrode, carbon rod as the counter electrode, and cobalt and aluminum molybdenum disulfide doped reduced graphene oxide aerogel as working electrode.