• 专利标题:   Manufacture of zinc oxide/graphene composite for lithium ion battery, involves adding zinc salt to graphene oxide dispersion, adjusting pH, hydrothermally reacting, cooling to room temperature, washing, vacuum-drying and calcining.
  • 专利号:   CN104022268-A
  • 发明人:   LIU Y, ZHANG J, ZHANG L, GUO S
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   H01M004/36
  • 专利详细信息:   CN104022268-A 03 Sep 2014 H01M-004/36 201479 Pages: 8 Chinese
  • 申请详细信息:   CN104022268-A CN10238248 30 May 2014
  • 优先权号:   CN10238248

▎ 摘  要

NOVELTY - Zinc salt is added to graphene oxide dispersion, stirred uniformly, and sodium hydroxide solution or aqueous ammonia is added to adjust the pH. 100 ml Obtained mixed solution is subjected to hydrothermal reaction at 80-180 degrees C for 2-10 hours, and naturally cooled to room temperature. The resultant material is washed with water and ethanol each three times, vacuum-dried, and partial reduction process is carried out. The obtained composite material is calcined under inert atmosphere, and cooled to room temperature to obtain zinc oxide/graphene composite. USE - Manufacture of zinc oxide/graphene composite used as cathode material for lithium ion battery. ADVANTAGE - The method efficiently and economically provides zinc oxide/graphene composite having excellent electroconductivity, volume expansion effect and cycling stability, by simple method. DETAILED DESCRIPTION - 0.008-0.08 g Graphite oxide is added to 80 ml solvent, and the mixture is placed in ultrasonic cleaning instrument under ultrasonic frequency of 40 kHz and sonicated for 0.5-3 hours to obtain graphene oxide dispersion. 0.002-0.3000 g Zinc salt is added to prepared graphene oxide dispersion, stirred uniformly, and sodium hydroxide solution or aqueous ammonia is added to adjust the pH of the mixed solution to 8-13. 100 ml Mixed solution is subjected to hydrothermal reaction in a hydrothermal reaction vessel, at 80-180 degrees C for 2-10 hours, and naturally cooled to room temperature. The resultant material is washed with water and ethanol each three times, vacuum-dried, and partial reduction process is carried out. The obtained composite material is calcined under inert atmosphere, and cooled to room temperature to obtain zinc oxide/graphene composite.