• 专利标题:   Flakes of graphene surface-modified nanoparticles composite of carbon monoxide-titanium-noble metal, prepared by e.g. dispersing flakes of graphene or graphene oxide in organic solvent and adding titanium compounds and noble metal compounds.
  • 专利号:   PL411401-A1
  • 发明人:   JURECZKO J, KUNICKI A, JASTRZEBSKA A, OLSZYNA A
  • 专利权人:   POLITECHNIKA WARSZAWSKA
  • 国际专利分类:   B82Y040/00, C01B031/00, C01G023/047, C01G005/00, C01G055/00, C01G007/00
  • 专利详细信息:   PL411401-A1 29 Aug 2016 C01B-031/00 201669 Pages: 1
  • 申请详细信息:   PL411401-A1 PL411401 26 Feb 2015
  • 优先权号:   PL411401

▎ 摘  要

NOVELTY - Flakes of graphene surface-modified nanoparticles composite of carbon monoxide-titanium-noble metal, is disclosed. Preparation of modified graphene flakes, comprises dispersing flakes of graphene or graphene oxide in an organic solvent comprising 3-9C aliphatic hydrocarbons, adding titanium compounds (IIa)-(IIe), and noble metal compounds (IIf), stirring in presence of dry or humid air, removing the solvent, drying the residue, and subjecting to thermal decomposition in the presence of air at 200-700 degrees C. USE - Used as flakes of graphene surface-modified nanoparticles composite of carbon monoxide-titanium-noble metal. DETAILED DESCRIPTION - Flakes of graphene surface-modified nanoparticles composite of carbon monoxide-titanium-noble metal, is disclosed. Preparation of modified graphene flakes, comprises dispersing flakes of graphene or graphene oxide in an organic solvent comprising 3-9C aliphatic hydrocarbons, adding titanium compounds of formulae (IIa)-(IIe), and noble metal compound of formulae (IIf), stirring in presence of dry or humid air, removing the solvent, drying the residue, and subjecting to thermal decomposition in the presence of air at 200-700 degrees C. The titanium compound is present in the organic solvent at 0.001-10 mole/l, and the noble metal is present in the organic solvent at 0.001-10 mole/l. R, R11 = 1-9C alkyl; n = 3-4; x, m = 3; y = not defined; and R12 = 1-9C alkyl or inorganic substituent of groups V-VII containing carbonates, hydroxides, chlorides, sulfides, fluorides, iodides, nitrates and/or thiocyanates.