• 专利标题:   Precursor composite, useful in electrode material for alkali ion battery, comprises graphene oxide with a specified value of carbon and oxygen ratio, and electrochemically active material including tetravalent vanadium oxohydroxide.
  • 专利号:   EP2747175-A1, JP2014123564-A, KR2014081732-A, US2014178763-A1, CN103887480-A, TW201431162-A, JP5763741-B2, US9225009-B2, KR1592072-B1, CN103887480-B, TW623134-B1, EP2747175-B1
  • 发明人:   METTAN Y, MYTAN Y
  • 专利权人:   BELENOS CLEAN POWER HOLDING AG, BELENOS CLEAN POWER HOLDING AG, BELENOS CLEAN POWER HOLDING AG, BELENOS CLEAN POWER HOLDING AG, BALENOS CLEAN ENERGY CO LTD, BELENOS CLEAN ENERGY CO LTD
  • 国际专利分类:   H01M010/052, H01M010/0525, H01M004/04, H01M004/1391, H01M004/36, H01M004/485, H01M004/583, H01M004/62, C01B031/02, C01G031/00, H01M004/48, H01M004/131, H01M004/13, H01M010/54, H01M004/133, H01M004/1393
  • 专利详细信息:   EP2747175-A1 25 Jun 2014 H01M-004/04 201451 Pages: 18 English
  • 申请详细信息:   EP2747175-A1 EP194702 27 Nov 2013
  • 优先权号:   EP198987, EP150846

▎ 摘  要

NOVELTY - Precursor composite for an electrode material, comprises graphene oxide with a carbon and oxygen (C:O) ratio of 2.5:3.5, and electrochemically active material (EAM) comprising a tetravalent vanadium oxohydroxide. USE - The precursor composite is useful in an electrode material of an electrochemical cell, which is useful for an alkali metal or alkali ion battery (all claimed). ADVANTAGE - The precursor composite can be economically and easily prepared using the improved amount of graphene oxide and electrochemically active materials having unique properties, and exhibits enhanced electronic conductivity property. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) preparing the precursor composite, comprising mixing the tetravalent vanadium oxohydroxide with an aqueous graphene oxide solution; and (2) producing an electrode material from the precursor composite comprising (a) drying the precursor composite, (b) heating the dry precursor composite to a temperature of at least 50 degrees C but below the decomposition temperature of the vanadium oxohydroxide and for a time sufficient to induce the desired reduction of the graphene oxide with respective change in the oxidation state of the transition metal in the vanadium oxohydroxide. DESCRIPTION OF DRAWING(S) - The figure shows a scanning electron microscope (SEM) image of the H4V3O8-graphene oxide composite.