• 专利标题:   Preparation of photocurable polyethylene terephthalate/graphene thermally conductive film involves preparing graphene heat-dissipating slurry by mixing graphene and solvent, shearing, and adding urea-formaldehyde resin and curing agent.
  • 专利号:   CN108250472-A
  • 发明人:   LIN Q
  • 专利权人:   HUNAN GONSION GRAPHITE TECHNOLOGY CO LTD
  • 国际专利分类:   C08J007/04, C08L067/02, C09D161/06, C09D007/61
  • 专利详细信息:   CN108250472-A 06 Jul 2018 C08J-007/04 201853 Pages: 7 Chinese
  • 申请详细信息:   CN108250472-A CN10040584 16 Jan 2018
  • 优先权号:   CN10040584

▎ 摘  要

NOVELTY - Preparation of photocurable polyethylene terephthalate/graphene thermally conductive film involves preparing graphene heat-dissipating slurry by mixing 6-12 pts. wt. graphene and 12-24 pts. wt. solvent under ultrasonic vibrations for 40-60 minutes, and shearing to obtain composite slurry material; adding 50-70 pts. wt. urea-formaldehyde resin to 12-30 pts. wt. composite slurry material, mixing, adding 5-8 pts. wt. curing agent and 3-6 pts. wt. carbon nanotubes, and stirring under 1000-1200 revolutions/minute (rpm) for 2-4 hours to obtain initial product of graphene heat-dissipating slurry; adding 2-5 pts. wt. thermally conductive metal powder, 12-16 pts. wt. antifoaming agent and 1-5 pts. wt. antioxidant, mixing, adding 50-70 pts. wt. organic monomer and 1-5 pts. wt. crosslinking agent, stirring under 1200-1500 rpm for 2-3 hours; subjecting 30 mu m thick polyethylene terephthalate to corona treatment; adding photocuring agent to first obtained product, and mixing uniformly. USE - Method for preparing photocurable polyethylene terephthalate/graphene thermally conductive film (claimed). ADVANTAGE - The product has excellent heat conducting coefficient, three-dimensional network-shaped structure and thermal diffusion coefficient. DETAILED DESCRIPTION - Preparation of photocurable polyethylene terephthalate/graphene thermally conductive film comprises preparing graphene heat-dissipating slurry by mixing 6-12 pts. wt. graphene and 12-24 pts. wt. solvent under ultrasonic vibrations for 40-60 minutes, and shearing to obtain composite slurry material; adding 50-70 pts. wt. urea-formaldehyde resin to 12-30 pts. wt. composite slurry material, mixing, adding 5-8 pts. wt. curing agent and 3-6 pts. wt. carbon nanotubes, and stirring under 1000-1200 revolutions/minute (rpm) for 2-4 hours to obtain initial product of graphene heat-dissipating slurry; adding 2-5 pts. wt. thermally conductive metal powder, 12-16 pts. wt. antifoaming agent and 1-5 pts. wt. antioxidant, mixing, adding 50-70 pts. wt. organic monomer and 1-5 pts. wt. crosslinking agent, stirring under 1200-1500 rpm for 2-3 hours; subjecting 30 mu m thick polyethylene terephthalate to corona treatment; adding photocuring agent to first obtained product, mixing uniformly, applying mixed slurry to corona-treated polyethylene terephthalate film by bench coater; and placing in UV light or laser beam atmosphere at wavelength of 365-405 nm for 1-2 minutes, drying, curing at 25 degrees C 1.0-2.0 hours, shrinking, deforming, slowly raising temperature to 100-200 degrees C for 1.0-3.0 hours, and trimming.