• 专利标题:   Multi-size gradient filler modified solvent-free heavy-duty anticorrosive coating comprises film-forming substance, curing agent, gradient-type filler, and auxiliary agent.
  • 专利号:   CN112538308-A
  • 发明人:   TIAN Y, GUAN Z, LI J, ZHANG Y, HUANG D
  • 专利权人:   AECC BEIJING AERONAUTICAL MATERIALS INST
  • 国际专利分类:   C09D163/02, C09D007/62, C09D007/61, C09D005/08
  • 专利详细信息:   CN112538308-A 23 Mar 2021 C09D-163/02 202132 Pages: 9 Chinese
  • 申请详细信息:   CN112538308-A CN11114588 16 Oct 2020
  • 优先权号:   CN11114588

▎ 摘  要

NOVELTY - Multi-size gradient filler modified solvent-free heavy-duty anticorrosive coating comprises 40-50 wt.% film-forming substance, 20-30 wt.% curing agent, 8-30 wt.% gradient-type filler and an auxiliary agent (remaining amount). The film-forming substance is a modified bisphenol A epoxy resin. The curing agent is cardanolamine. The filler is modified graphene, fluorophlogopite, and glass flakes. The auxiliary agent comprises active diluents, wetting and dispersing agents, and anti-sagging additives. The reactive diluent is a derivative of glycidyl isopropyl ether or a monofunctional group of glycidyl isopropyl ether. The graphene has a diameter of 30-40 mu m. The structure of the fluorophlogopite mica is KMg3 (AlSi3O10) F2, and its diameter is 45-70 mu m. The glass flakes have a diameter of 75-150 mu m. USE - Used as multi-size gradient filler modified solvent-free heavy-duty anticorrosive coating. ADVANTAGE - The coating: has excellent corrosion resistance and oil resistance; and overcomes the problem of insufficient corrosion resistance of existing anticorrosive coatings in marine environments. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the multi-size gradient filler modified solvent-free heavy-duty anticorrosive coating, comprising (i) mixing ethanol and water in a volume ratio of 3:1, then mixing the mixture with graphene oxide, stirring and ultrasonically dispersing the mixture to obtain a uniform graphene oxide suspension, and then re-directing it according to the stoichiometric ratio, adding gamma-aminopropyltriethoxysilane modified graphene oxide, stirring in an oil bath at 70 degrees C, condensing and refluxing for 6-8 hours to make the reaction complete, performing vacuum filtration, using ethanol/water, washing mixed solution and critically freezing and drying to obtain amino-modified graphene, (ii) weighing the film-forming material, fillers and additives, and (iii) adding fillers and additives to the film-forming material, stirring at a high speed with a mixer for at least 1 minute, placing in a sand mill to grind until the discharge viscosity is 15000-19000 MPa.s.