• 专利标题:   Catalyst for direct conversion of synthesis gas to produce low-carbon olefins, comprises component comprising metal oxide containing manganese oxide, cerium dioxide and manganese aluminum oxide, and component comprising molecular sieve.
  • 专利号:   CN112973781-A, CN112973781-B
  • 发明人:   JIAO F, DING Y, PAN X, BAO X
  • 专利权人:   CAS DALIAN CHEM PHYSICAL INST
  • 国际专利分类:   B01J023/06, B01J023/08, B01J023/10, B01J023/26, B01J023/34, B01J029/83, B01J029/84, B01J029/85, B01J037/04, C07C001/04, C07C011/04, C07C011/06
  • 专利详细信息:   CN112973781-A 18 Jun 2021 B01J-029/83 202169 Pages: 14 Chinese
  • 申请详细信息:   CN112973781-A CN11289554 14 Dec 2019
  • 优先权号:   CN11289554

▎ 摘  要

NOVELTY - A catalyst comprises component (A) comprising metal oxide as active material and component (B) comprising molecular sieve with LEV topology. The metal oxide is one or more of manganese oxide, manganese chromium oxide, manganese aluminum oxide, manganese zirconium oxide, manganese indium oxide, zinc oxide, zinc chromium oxide, zinc aluminum oxide, zinc gallium oxide, zinc indium oxide, cerium dioxide, gallium trioxide, indium trioxide, zinc-aluminum-manganese oxide and indium-gallium-manganese oxide. The specific surface area of manganese oxide, zinc oxide, cerium dioxide, gallium trioxide and indium trioxide is 1-100 m2/g, and the specific surface area of manganese chromium oxide, manganese aluminum oxide, manganese zirconium oxide, manganese indium oxide, zinc chromium oxide, zinc aluminum oxide, zinc-aluminum-manganese oxide and indium-gallium-manganese oxide is 5-150 m2/g. USE - Catalyst used for direct conversion of synthesis gas to produce low-carbon olefins (claimed). ADVANTAGE - The catalyst can be effectively used in direct conversion of synthesis gas to produce olefin with high yield, high 2C and 3C selectivity and low by-product methane selectivity. DETAILED DESCRIPTION - A catalyst comprises component (A) comprising metal oxide as active material and component (B) comprising molecular sieve with LEV topology. The metal oxide is one or more of manganese oxide (MnOx), manganese chromium oxide (MnCryO(x+1.5y)), manganese aluminum oxide (MnAlyO(x+1.5y)), manganese zirconium oxide (MnZryO(x+2y)), manganese indium oxide (MnInyO(x+1.5y)), zinc oxide, zinc chromium oxide (ZnCryO(x+1.5y)), zinc aluminum oxide (ZnAlyO(1+1.5y)), zinc gallium oxide (ZnGayO(1+1.5y)), zinc indium oxide (ZnInyO(2+1.5y)), cerium dioxide, gallium trioxide, indium trioxide, zinc-aluminum-manganese oxide (ZnyAlzMnO(x+1.5y+1.5z)) and indium-gallium-manganese oxide (InyGazMnO(x+1.5y+1.5z)). The specific surface area of manganese oxide, zinc oxide, cerium dioxide, gallium trioxide and indium trioxide is 1-100 m2/g, and the specific surface area of manganese chromium oxide, manganese aluminum oxide, manganese zirconium oxide, manganese indium oxide, zinc chromium oxide, zinc aluminum oxide, zinc-aluminum-manganese oxide and indium-gallium-manganese oxide is 5-150 m2/g. x = 1-3.5; y = 0.1-10;and z = 0.1-10. An INDEPENDENT CLAIM is included for method for directly converting synthesis gas to produce low-carbon olefins, which involves using the synthesis gas as the reaction raw material to carry out the conversion reaction on fixed bed or moving bed comprising the catalyst.