• 专利标题:   Preparing modified polylactic acid material for preparing polylactic acid composite material, comprises e.g. mixing modified nanocellulose and lactic acid in water, heating, removing separated moisture from reaction system, pulverizing, subjecting to solid phase condensation polymerization.
  • 专利号:   CN113845652-A
  • 发明人:   YANG C, XU J, HE Y, HAO S, TIAN J
  • 专利权人:   BEIJING GRAPHENE TECHNOLOGY RES INST CO
  • 国际专利分类:   C08G063/688, C08G063/80, C08G063/87, C08L067/04
  • 专利详细信息:   CN113845652-A 28 Dec 2021 C08G-063/688 202235 Chinese
  • 申请详细信息:   CN113845652-A CN11446329 01 Dec 2021
  • 优先权号:   CN11446329

▎ 摘  要

NOVELTY - Preparing modified polylactic acid material comprises mixing the modified nanocellulose and lactic acid in water to obtain a mixed dispersion, and the modified nanocellulose has a sulfonic acid group and a hydroxy group, heating the mixed dispersion and stirring until the solid content of the mixed dispersion is 80-95% at 140-180degrees Celsius and the pressure of 2-6 kpa for 1-12 hours in-situ catalytic melt condensation polymerization reaction, removing the separated moisture from the reaction system to obtain a nanocellulose polylactic acid prepolymer composite material, pulverizing the nanocellulose polylactic acid prepolymer composite material to obtain powder, keeping the powder at 70-120degrees Celsius for 0.1-5 hours, subjecting to solid phase condensation polymerization for 0.1-20 hours at 120-160degrees Celsius and a pressure of less than or equal to 2 kpa. USE - The modified polylactic acid material is used as nucleating agent, toughening agent or plasticizer of polylactic acid for preparing polylactic acid composite material (all claimed). DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: modified polylactic acid material prepared by the above-mentioned method; preparation polylactic acid composite material, comprising blending polylactic acid with the modified polylactic acid material.