• 专利标题:   Preparing one-dimensional ordered titanium-base titanium dioxide nano-wire array film with ultra-high aspect ratio involves soaking industrial pure titanium in absolute ethyl alcohol, ultrasonic cleaning, after cleaning, dipping etching liquid, soaking processed titanium foil hydrothermal reaction.
  • 专利号:   CN114950398-A, CN114950398-B
  • 发明人:   LIAO L, LIAN P, HAO X, QIN A
  • 专利权人:   UNIV GUILIN TECHNOLOGY
  • 国际专利分类:   B01J021/06, B01J035/02, B01J035/06, B82Y030/00, B82Y040/00, C01G023/047
  • 专利详细信息:   CN114950398-A 30 Aug 2022 B01J-021/06 202293 Chinese
  • 申请详细信息:   CN114950398-A CN10664016 12 Jun 2022
  • 优先权号:   CN10664016

▎ 摘  要

NOVELTY - Preparing one-dimensional ordered titanium-base titanium dioxide nano-wire array film with an ultra-high aspect ratio involves soaking the industrial pure titanium in absolute ethyl alcohol or acetone at 50-70 °C, ultrasonic cleaning for 10 minutes, after cleaning, dipping it in etching liquid for micro thinning and surface texturing treatment, soaking the processed titanium foil into a hydrothermal reaction mixed solution containing 1-5 mol/L of sodium hydroxide and graphene quantum dot solution 0.25-1 g/L, and transfer to a stainless steel reactor with polyphenol PPL lining, reacting for 18-24 hours in 0-220 ℃ oven, and cooling to room temperature, taking out, deionized water washing, obtain the intermediate product Na2Ti2O5-H2O nanowire film, soaking the prepared intermediate product Na2Ti2O5-H2O nanowire film into 0.1-1 mol/L of diluted hydrochloric acid or 0.1-1 mol/L diluted nitric acid solution for 5-10 minutes. USE - Method for preparing one-dimensional ordered titanium-base titanium dioxide nano-wire array film with an ultra-high aspect ratio, ADVANTAGE - The method has good light permeability, and a large specific surface area, and has high application value in the photo-catalysis and photo-electric energy conversion field. DETAILED DESCRIPTION - Preparing one-dimensional ordered titanium-base titanium dioxide nano-wire array film with an ultra-high aspect ratio involves soaking the industrial pure titanium in absolute ethyl alcohol or acetone at 50-70 °C, ultrasonic cleaning for 10 minutes, after cleaning, dipping it in etching liquid for micro thinning and surface texturing treatment, soaking the processed titanium foil into a hydrothermal reaction mixed solution containing 1-5 mol/L of sodium hydroxide and graphene quantum dot solution 0.25-1 g/L, and transfer to a stainless steel reactor with polyphenol PPL lining, reacting for 18-24 hours in 0-220 ℃ oven, and cooling to room temperature, taking out, deionized water washing, obtain the intermediate product Na2Ti2O5-H2O nanowire film, soaking the prepared intermediate product Na2Ti2O5-H2O nanowire film into 0.1-1 mol/L of diluted hydrochloric acid or 0.1-1 mol/L diluted nitric acid solution for 5-10 minutes to obtain the intermediate product H2Ti2O5*H2O nanowire film, putting the prepared H2Ti2O5-H2O nanowire film in 500-600 ℃ muffle furnace for air calcining for 1-2 hours naturally cooling to room temperature to obtain the one-dimensional ordered titanium-based titanium dioxide nano-wire array film.