• 专利标题:   Preparing graphene-based alkenyl epoxy resin heat-conducting composite material, involves reacting pyrenyl hyperbranched polyethylene terpolymer, functional assistant, mixing obtained graphene dispersion liquid with epoxy resin, chloroform.
  • 专利号:   CN114369337-A
  • 发明人:   YE H, WANG Q, WANG W, XU L
  • 专利权人:   UNIV ZHEJIANG TECHNOLOGY, ZHEJIANG YUANSHENG PLASTIC IND CO LTD
  • 国际专利分类:   C08K003/04, C08K009/04, C08L063/00, C09K005/14
  • 专利详细信息:   CN114369337-A 19 Apr 2022 C08L-063/00 202282 Chinese
  • 申请详细信息:   CN114369337-A CN10030488 12 Jan 2022
  • 优先权号:   CN10030488

▎ 摘  要

NOVELTY - Preparing graphene-based alkenyl epoxy resin heat-conducting composite material involves preparing pyrenyl (Py) hyperbranched polyethylene terpolymer (HBPE) composite (HBPE-Py-Poly Glycidyl Methacrylate (PGMA)); taking pyrenyl hyperbranched polyethylene terpolymer (HBPE-Py-PGMA) as stripping stability and functional assistant, ultrasonically stripping natural flaky graphite in organic solvent, and removing un-stripped natural flaky graphite and excessive HBPE-Py-PGMA through centrifugation to obtain HBPE-Py-PGMA functional graphene dispersion liquid; mixing HBPE-Py-PGMA functionalized graphene dispersion liquid, epoxy resin and chloroform solvent, and stirring at room temperature for 1-3 hours to uniformly mixed solution; adding curing agent, stirring for 0.5-1.5 hours at room temperature to uniformly mix solution; carrying out vacuum filtration on obtained mixed solution in vacuum oven at room temperature to remove bubbles. USE - Method for preparing graphene-based alkenyl epoxy resin heat-conducting composite material. ADVANTAGE - The method for preparing graphene-based alkenyl epoxy resin heat-conducting composite material is simple, has short preparation period, and good heat-conducting performance. DETAILED DESCRIPTION - Preparing graphene-based alkenyl epoxy resin heat-conducting composite material involves preparing pyrenyl (Py) hyperbranched polyethylene terpolymer pyrenyl (Py) hyperbranched polyethylene terpolymer (HBPE) composite (HBPE-Py-Poly Glycidyl Methacrylate (PGMA)); taking pyrenyl hyperbranched polyethylene terpolymer (HBPE-Py-PGMA) as stripping stability and functional assistant, ultrasonically stripping natural flaky graphite in organic solvent, and removing un-stripped natural flaky graphite and excessive HBPE-Py-PGMA through centrifugation to obtain HBPE-Py-PGMA functional graphene dispersion liquid; mixing HBPE-Py-PGMA functionalized graphene dispersion liquid, epoxy resin and chloroform solvent, and stirring at room temperature for 1-3 hours to uniformly mixed solution; adding curing agent, stirring for 0.5-1.5 hours at room temperature to uniformly mix solution; carrying out vacuum filtration on obtained mixed solution in vacuum oven at room temperature to remove bubbles; pouring obtained mixed solution in polytetrafluoroethylene mold, pre-curing at 40-60℃ for 0.5-1 hour, and curing at 60-80℃ for 6-10 hours in constant-temperature air-blast drying oven to obtain graphene-based epoxy resin composite material, where graphene-based epoxy resin heat-conducting composite material comprises 1.0-4.0 wt.% graphene.