• 专利标题:   PTFE composite material contains titanium silicon carbide, PTFE, carbon fiber, steel fiber, fluororubber powder, graphene oxide, titanium aluminum carbide, silicon dioxide, aminopropyltriethoxysilane and ethanol.
  • 专利号:   CN106046637-A
  • 发明人:   HU G
  • 专利权人:   ANHUI RONGDA VALVE CO LTD
  • 国际专利分类:   C08J007/04, C08K013/06, C08K003/04, C08K003/14, C08K003/34, C08K003/36, C08K007/06, C08K009/02, C08K009/06, C08L027/12, C08L027/18
  • 专利详细信息:   CN106046637-A 26 Oct 2016 C08L-027/18 201714 Pages: 5 Chinese
  • 申请详细信息:   CN106046637-A CN10473179 23 Jun 2016
  • 优先权号:   CN10473179

▎ 摘  要

NOVELTY - A PTFE composite material comprises 5-10 pts. wt. titanium silicon carbide, 80-90 pts. wt. PTFE, 10-15 pts. wt. carbon fiber, 5-10 pts. wt. steel fiber, 15-20 pts. wt. fluororubber powder, 1-3 pts. wt. graphene oxide, 5-10 pts. wt. titanium aluminum carbide, 5-10 pts. wt. silicon dioxide, 15-20 pts. wt. ( gamma )-aminopropyltriethoxysilane, 30-40 pts. wt. 95% ethanol, acetic acid, 15-20 pts. wt. polyisocyanate JQ-1, 15-20 pts. wt. dimethylformamide, 10-15 pts. wt. 4-dimethylaminopyridine, 15-20 pts. wt. dicyclohexylcarbodiimide, and 90-100 pts. wt. water. USE - PTFE composite material (claimed). ADVANTAGE - The composite material has increased wear-resisting property, and is produced using simple process at reduced cost. DETAILED DESCRIPTION - A PTFE composite material comprises 5-10 pts. wt. titanium silicon carbide, 80-90 pts. wt. PTFE, 10-15 pts. wt. carbon fiber, 5-10 pts. wt. steel fiber, 15-20 pts. wt. fluororubber powder, 1-3 pts. wt. graphene oxide, 5-10 pts. wt. titanium aluminum carbide, 5-10 pts. wt. silicon dioxide, 15-20 pts. wt. ( gamma )-aminopropyltriethoxysilane, 30-40 pts. wt. 95% ethanol, acetic acid, 15-20 pts. wt. polyisocyanate JQ-1, 15-20 pts. wt. dimethylformamide, 10-15 pts. wt. 4-dimethylaminopyridine, 15-20 pts. wt. dicyclohexylcarbodiimide, and 90-100 pts. wt. water. The carbon fiber median length is 75-150 mu m. The median length of steel fiber is 50-150 mu m. The fluororubber powder particle size is 80-200 mesh. An INDEPENDENT CLAIM is included for preparation of PTFE composite material, which involves adding carbon fiber to 20-25 pts. wt. 95% ethanol solvent, ultrasonically dispersing, adding acetic acid to adjust the pH to 4-5, adding ( gamma )-aminopropyltriethoxysilane, stirring for 8-15 hours, washing with deionized water, vacuum drying, oxidizing graphene oxide to graphene peroxide with remaining 95% ethanol solvent, adding graphene oxide to dimethylformamide, ultrasonically treating for 2-3 hours, stirring, adding 4-dimethylaminopyridine, dicyclohexylcarbodiimide and carbon fiber, reacting at room temperature for 18-36 hours, washing with deionized water, vacuum drying to obtain graphene grafted carbon fiber, adding polyisocyanate JQ-1, adding dry steel fiber, titanium silicon carbide and titanium aluminum carbide, stirring for 1-3 hours, washing, drying, mixing carbon fibers with 70-75 pts. wt. PTFE, cooling, sintering in air atmosphere at 360-390 degrees C to obtain plate-shaped sample with diameter 150-250 mm and thickness 3-4 mm, immersing the plate-shaped sample in dip coating solution, drying in oven at 80-100 degrees C after 4-8 minutes, and sintering at 120-200 degrees C for 10-30 minutes, where dip coating solution is prepared by grinding silicon dioxide, dispersing remaining PTFE and remaining ( gamma )-aminopropyltriethoxysilane in water, and ultrasonically dispersing.