• 专利标题:   Preparation of graphene material used as positive electrode material in lithium-ion battery used in digital product, involves adding perylene tetracarboxylic dianhydride and 4,4'-diaminodiphenylmethane to flask, adding N-methylpyrrolidone, isoquinoline and nitrogen-doped graphene, and refluxing.
  • 专利号:   CN114684812-A
  • 发明人:   CAO C
  • 专利权人:   ANHUI ZHENGXI BIAOWANG NEW ENERGY CO LTD
  • 国际专利分类:   C01B032/184, C01B032/194, H01M010/0525, H01M004/587, H01M004/62
  • 专利详细信息:   CN114684812-A 01 Jul 2022 C01B-032/184 202283 Chinese
  • 申请详细信息:   CN114684812-A CN11581688 28 Dec 2020
  • 优先权号:   CN11581688

▎ 摘  要

NOVELTY - Preparation of graphene material, involves (s1) preparing graphite oxide by Hummers method, (s2) adding 2 mg graphite oxide powder to a beaker, adding 40 ml deionized water, ultrasonically dispersing for 15 minutes, adding cetyltrimethylammonium bromide, ammonium persulfate, and pyrrole, stirring at 0℃ for 24 hours, drying, adding the dried material to 30 ml potassium hydroxide solution, stirring for 24 hours, filtering, drying, heating to 800℃ under nitrogen protection, calcining at constant temperature for 2 hours to obtain nitrogen-doped graphene, and (s3) adding 2.91 g perylene tetracarboxylic dianhydride and 1.47 g 4,4'-diaminodiphenylmethane to three-necked flask, adding 50 ml N-methylpyrrolidone as reaction solvent, adding 0.04 g isoquinoline as catalyst and 5-10 g nitrogen-doped graphene, and refluxing and reacting at 203℃ under nitrogen protection for 4 hours, to synthesize polyimide and load it on graphene. USE - Preparation of graphene material used as positive electrode material (all claimed) in lithium-ion battery used in digital products, such as mobile phone and notebook computer. ADVANTAGE - The graphene material has excellent performance, high lithium storage capacity and capacity retention rate.