• 专利标题:   Metal processing water lubricating nano additive, prepared by adjusting pH of graphene quantum dot solution containing carboxy groups, uniformly ultrasonically dispersing, performing deoxygenation treatment and dialyzing.
  • 专利号:   CN111944586-A
  • 发明人:   XU Y, LIU K, ZHENG Q, BAO Y, YAO L
  • 专利权人:   UNIV HEFEI TECHNOLOGY
  • 国际专利分类:   C08F220/54, C08F222/38, C08F292/00, C10M161/00, C10N030/04, C10N030/06, C10N040/22
  • 专利详细信息:   CN111944586-A 17 Nov 2020 C10M-161/00 202099 Pages: 7 Chinese
  • 申请详细信息:   CN111944586-A CN10872316 26 Aug 2020
  • 优先权号:   CN10872316

▎ 摘  要

NOVELTY - Metal processing water lubricating nano additive, prepared by (i) adjusting the pH of the graphene quantum dot solution containing carboxy groups at a concentration of 15-25 g/l to neutral; (ii) adding 1.5-2.5 g N-isopropylacrylamide monomer, 0.02-0.04 g N,N'-methylenebispropylamide crosslinking agent, 0.01-0.03 g sodium lauryl sulfate, and 2-10 ml above neutral solution of graphene quantum dots sequentially into a beaker containing 120 ml deionized water, uniformly ultrasonically dispersing to form the first dispersed phase, and ultrasonically dispersing uniformly to form a second dispersed phase; and (iii) placing the first dispersed phase in a four-necked flask and letting nitrogen gas into it, performing deoxygenation treatment, and heating the solution to 65-70 degrees C, changing deionized water every 5-7 hours, and dialyzing for 6-8 days to obtain metal processing water-lubricated nano-additive graphene quantum dot-polyN-isopropylacrylamide composite microgel, is claimed. USE - Used as metal processing water lubricating nano additive. ADVANTAGE - The method solves the problem of agglomeration of graphene quantum dots, The composite microgel has a particle size of 60-100nm, uniform and controllable particle size, and good dispersion, excellent lubricating properties for titanium alloy/hard alloy friction pairs and good application prospects in titanium alloy processing and other fields. DETAILED DESCRIPTION - Metal processing water lubricating nano additive, prepared by (i) adjusting the pH of the graphene quantum dot solution containing carboxy groups at a concentration of 15-25 g/l to neutral; (ii) adding 1.5-2.5 g N-isopropylacrylamide monomer, 0.02-0.04 g N,N'-methylenebispropylamide crosslinking agent, 0.01-0.03 g sodium lauryl sulfate, and 2-10 ml above neutral solution of graphene quantum dots sequentially into a beaker containing 120 ml deionized water, uniformly ultrasonically dispersing to form the first dispersed phase, dissolving 1-2 g potassium persulfate in 100 ml deionized water that has undergone deoxygenation treatment, and ultrasonically dispersing uniformly to form a second dispersed phase, where the ultrasonic power is 200-400 W, and the ultrasonic time is 20-40 minutes; and (iii) placing the first dispersed phase in a four-necked flask and letting nitrogen gas into it, performing deoxygenation treatment, and heating the solution to 65-70 degrees C, dropping 3-8 mk of the second dispersed phase at a dropping rate of 50-70 drops/minute, reacting for 4-5 hours, using a dialysis bag with a molecular weight cutoff of 3500D, changing deionized water every 5-7 hours, and dialyzing for 6-8 days to obtain metal processing water-lubricated nano-additive graphene quantum dot-polyN-isopropylacrylamide composite microgel, is claimed.