• 专利标题:   Three-dimensional nitrogen-doped graphene/gamma-iron oxide/silver composite photocatalyst for photocatalytic degradation of dyes, includes a three-dimensional nitrogen-doped graphene/gamma-iron oxide composite material.
  • 专利号:   CN112892576-A, CN112892576-B
  • 发明人:   SUN X, SHAN S, YAO X, XIE Y
  • 专利权人:   UNIV NORTHWESTERN POLYTECHNICAL
  • 国际专利分类:   B01J027/24, B01J035/10, C02F001/30, C02F101/30
  • 专利详细信息:   CN112892576-A 04 Jun 2021 B01J-027/24 202157 Pages: 15 Chinese
  • 申请详细信息:   CN112892576-A CN10119864 28 Jan 2021
  • 优先权号:   CN10119864

▎ 摘  要

NOVELTY - Three-dimensional nitrogen-doped graphene/gamma-iron oxide ( gamma -Fe2O3)/silver (Ag) composite photocatalyst includes a three-dimensional nitrogen-doped graphene/ gamma -Fe2O3 composite material, and Ag nanoparticles supported on the composite material. The three-dimensional nitrogen-doped graphene/ gamma -Fe2O3/Ag composite photocatalyst has a three-dimensional network structure. The mass ratio of the nitrogen-doped graphene to the gamma -Fe2O3 particles is 1:0.5-2. The loading amount of the Ag nanoparticles is 10-30 wt.%. USE - Three-dimensional nitrogen-doped graphene/ gamma -Fe2O3/Ag composite photocatalyst used in the photocatalytic degradation of dyes (claimed). ADVANTAGE - The three-dimensional nitrogen-doped graphene/ gamma -Fe2O3/Ag composite photocatalyst adopts visible light-responsive gamma -Fe2O3 as a semiconductor photocatalyst and graphene oxide as a carrier, and after nitrogen doping and precious metal silver deposition are modified, a nitrogen-doped graphene/ gamma Fe2O3/Ag composite photocatalyst with a three-dimensional structure is obtained through reactive self-assembly. The catalyst has a larger specific surface area and enhances the adsorption effect, and the electron transport efficiency is higher, which can effectively inhibit the recombination of photo-generated electron-hole pairs, and at the same time has magnetic responsiveness and is easy to recycle. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing three-dimensional nitrogen-doped graphene/ gamma -Fe2O3 composite material, which involves dispersing graphene oxide in a liquid medium, adding urea, mixing uniformly, and then adding gamma -Fe2O3 particles and dodecane sodium benzene sulfonate, continue to mixing uniformly, and then reacting at 160-190 degrees C for 10-15 hours to obtain the three-dimensional nitrogen-doped graphene/ gamma -Fe2O3 composite material.