• 专利标题:   Synthesis of graphene oxide used for manufacturing membrane, involves mixing sulfuric acid and phosphoric acid, adding graphite powder, potassium permanganate and hydrogen peroxide, cooling mixture, diluting mixture with hydrochloric acid solution, and centrifuging.
  • 专利号:   WO2021230761-A2, WO2021230761-A3, US2023183072-A1
  • 发明人:   ALKHOUZAAM A A, QIBLAWEY H
  • 专利权人:   QATAR FOUND EDUCATION SCI COMMUNITY, QATAR FOUND EDUCATION SCI COMMUNITY
  • 国际专利分类:   C01B032/198, C01B032/225, C01B032/23, B01D067/00, B01D069/14, B01D071/02, B01D071/44, B01D071/68
  • 专利详细信息:   WO2021230761-A2 18 Nov 2021 C01B-032/198 202199 Pages: 40 English
  • 申请详细信息:   WO2021230761-A2 WOQA050009 15 May 2021
  • 优先权号:   US025471P, US17925492

▎ 摘  要

NOVELTY - Synthesis of graphene oxide involves mixing sulfuric acid and phosphoric acid, adding graphite powder and potassium permanganate, transferring the mixture to an oil bath, adding deionized water to the mixture, adding hydrogen peroxide, cooling the mixture at room temperature, diluting the mixture with hydrochloric acid solution, and centrifuging. The graphene oxide comprises high oxygen content, and is nitric oxide-free emission starting from natural graphite flakes. USE - Synthesis of graphene oxide used as high-antifoulant and antibacterial nanofiller for manufacturing membrane (claimed) for water treatment. ADVANTAGE - The method produces membranes with excellent mechanical properties, fouling resistance, antibacterial activity, and high flux recovery ratio. The functionalization of graphene oxide with dodecylamine ensures excellent degree of functionalization. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) functionalization of graphene oxide with dodecylamine, which involves dispersing graphene oxide in deionized water and dodecylamine in ethanol to form suspensions, ultrasonically-processing suspensions, and extracting dodecylamine functionalized graphene oxide; and (2) preparation of membrane, which involves adding dodecylamine functionalized graphene oxide to 1-methyl-2-pyrrolidinone to form a mixture, mixing polyvinylpyrrolidone and polysulfone in the mixture, and casting the mixture to form the membrane. The membrane comprises polysulfone-dodecylamine functionalized graphene oxide.