• 专利标题:   Preparing metals-organic frameworks-graphene composite material involves reacting graphene with metal salt, terephthalic acid and triethylene diamine, adding reactant to tetrahydrofuran/water/methanol mixed solution and purifying.
  • 专利号:   CN106430166-A, CN106430166-B
  • 发明人:   TU W, YAN Q
  • 专利权人:   UNIV WUHAN TECHNOLOGY
  • 国际专利分类:   C01B032/184, H01M004/90
  • 专利详细信息:   CN106430166-A 22 Feb 2017 C01B-032/184 201724 Pages: 12 Chinese
  • 申请详细信息:   CN106430166-A CN10960132 28 Oct 2016
  • 优先权号:   CN10960132

▎ 摘  要

NOVELTY - Method for preparing metals-organic frameworks (MOFs)-graphene composite material involves (a) using graphene oxide as a raw material, tetrahydrofuran as a reaction medium and sodium borohydride as a reducing agent to prepare graphene, (b) reacting graphene with metal salt, terephthalic acid and triethylene diamine, (c) adding the reactant to tetrahydrofuran/water/methanol mixed solution, (d) ultrasonically stirring at 80-180 degrees C for 12-72 hours and (e) purifying the reaction product to obtain MOFs-graphene composite material. USE - Method is useful for preparing MOFs-graphene composite material (claimed), which is useful in energy devices such as fuel cell catalyst, super capacitor, lithium ion battery cathode material and adsorbing material. ADVANTAGE - The method enables rapid and simple preparation of MOFs-graphene composite material at reduced temperature under mild reaction conditions in an environmentally-friendly manner.