• 专利标题:   Electronic component, e.g. multilayer capacitors, has body including stacked dielectric layers and internal electrodes, one of which includes particle including nickel and tin, and graphene layer, and external electrodes.
  • 专利号:   US2022157531-A1, KR2022066506-A, CN114512338-A, US11569039-B2
  • 发明人:   YOO W H, LEE E K, NA J Y, LEE S M, MOON L S, KWANG L E, YOU W H, LIU Y, LI E, LUO Z, LEE S
  • 专利权人:   SAMSUNG ELECTROMECHANICS CO, SAMSUNG ELECTROMECHANICS CO
  • 国际专利分类:   C04B035/01, H01G002/06, H01G004/008, H01G004/012, H01G004/12, H01G004/30, B22F001/00, H01B001/02, H01B001/04, H01G004/232
  • 专利详细信息:   US2022157531-A1 19 May 2022 H01G-004/30 202245 English
  • 申请详细信息:   US2022157531-A1 US375327 14 Jul 2021
  • 优先权号:   KR152613

▎ 摘  要

NOVELTY - An electronic component (100) comprises body (110) including a set of stacked dielectric layers and internal electrodes arranged with a corresponding dielectric layer interposed in between; and external electrodes (161, 162) arranged on the body and connected to the internal electrodes corresponding to it. One of the internal electrodes includes a particle including nickel (Ni) and tin (Sn), and a graphene layer arranged at a boundary of the particle. Ratio of Sn content to a total content of Ni and Sn is Sn/(Ni+Sn), and Sn/(Ni+Sn) of first region located inside the particle at a first distance from a boundary between the particle and the graphene layer is A1, Sn/(Ni+Sn) of a second region located inside the particle at a second distance from the boundary between the particle and the graphene layer is A2, the second distance is smaller than the first distance, and A1 is smaller than A2. USE - An electronic component, e.g. multilayer capacitors, such as a multilayer ceramic capacitor (MLCC). ADVANTAGE - The electronic component has improved reliability. The graphene layer helps to secure a target capacitance by improving connectivity of the internal electrodes. In addition, the graphene layer prevents tin from being diffused into the dielectric layer by trapping tin in the particles. As a a result, a decrease in capacitance due to diffusion of Sn into the dielectric layer may be prevented. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) conductive powder particle for internal electrodes, comprising metal powder particle, coating layer surrounding at least a portion of a surface of the metal powder particle and including Sn, and graphene surrounding at least a portion of a surface of the coating layer; and (2) manufacture of electronic component which involves forming an unsintered body including a set of unsintered dielectric layers and unsintered internal electrodes formed by applying a conductive paste including Ni, Sn, and graphene to the unsintered dielectric layers, and sintering the unsintered body to form a sintered body, where the conductive paste includes conductive powder particles including a metal powder particle including Ni, a coating layer formed to surround at least a portion of a surface of the metal powder particle and including Sn, and graphene formed to surround at least a portion of a surface of the coating layer. DESCRIPTION OF DRAWING(S) - The drawing shows a perspective view illustrating an electronic component. Electronic component (100) Body (110) External electrodes (161, 162)