• 专利标题:   New oligophenylene monomer useful for preparing a polymeric precursor for producing graphene nanoribbons useful in an electronic, optical, or optoelectronic device.
  • 专利号:   WO2013093756-A1, TW201331255-A, KR2014116112-A, EP2794476-A1, US2014353554-A1, CN104114489-A, JP2015504046-W, SG11201403360-A1, IN201404378-P4, IL233003-A1, CN104114489-B, RU2014129615-A, US9550678-B2, TW579316-B1, EP2794476-A4
  • 发明人:   SCHWAB M G, NARITA A, FENG X, MUELLEN K, MULLEN K, SCHWAB M G S, SCHVAB M G, MILLEN K
  • 专利权人:   BASF SE, MAX PLANCK GES FOERDERUNG WISSENSCHAFTEN, BASF CHINA CO LTD, SCHWAB M G, NARITA A, FENG X, MUELLEN K, BASF SE, MAX PLANCK GES FOERDERUNG WISSENSCHAFTEN, BASF SE, MAX PLANCK GES FOERDERUNG WISSENSCHAFTEN, BASF SE, MAX PLANCK GES FOERDERUNG WISSENSCHAFTEN, BASF SE, MAX PLANCK GES FOERDERUNG WISSENSCHAFTEN, BASF AG
  • 国际专利分类:   C01B031/02, C01B031/04, C08G061/10, C07C049/647, C07C049/683, C08F138/00, H01B001/04, C07C015/14, C07C017/266, B82Y030/00, B82Y040/00, C08F002/00, C08L065/00
  • 专利详细信息:   WO2013093756-A1 27 Jun 2013 C01B-031/04 201351 Pages: 41 English
  • 申请详细信息:   WO2013093756-A1 WOIB057377 17 Dec 2012
  • 优先权号:   US577689P, US14367041, KR719888

▎ 摘  要

NOVELTY - An oligophenylene monomer, is new. USE - The oligophenylene monomer is useful for the preparation of a polymeric precursor for producing graphene nanoribbons useful in an electronic, optical, or optoelectronic device (all claimed). ADVANTAGE - The oligophenylene monomer can be efficiently used in preparing a polymeric precursor used producing improved graphene nanoribbons for an electronic device. DETAILED DESCRIPTION - An oligophenylene monomer of general formula (I). R1 and R2=H, halogen, -OH, -NH2, -CN, -NO2 or a linear or branched, saturated or unsaturated 1-40C hydrocarbon residue, which can be substituted 1- to 5-fold with halogens (F, Cl, Br, I), -OR3, -NR32, -CN and/or -NO2, and where one or more CH2-groups can be replaced by -O-, -S-, -NR4-, -OC(O)- or -C(O)-, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; R3=H , 1-30C alkyl, 2-30C alkenyl, 2-30C alkynyl, 1-30C haloalkyl, 2-30C haloalkenyl, 2-30C haloalkynyl or 2-30C acyl; R4=H, 1-30C alkyl, 2-30C alkenyl, 2-30C alkynyl, 1-30C haloalkyl, 2-30C haloalkenyl, 2-30C haloalkynyl or 2-30C acyl; and m=0, 1 or 2. INDEPENDENT CLAIMS are: (1) a polymeric precursor for preparing graphene nanoribbons having repeating units of general formula (II); (2) a process for the production of graphene nanoribbons by cyclodehydrogenation of the polymeric precursor; (3) graphene nanoribbons, obtainable by the latter process; (4) a composition comprising one or more graphene nanoribbons dissolved or dispersed in a liquid medium; and (5) an electronic, optical, or optoelectronic device comprising a thin film semiconductor comprising one or more graphene nanoribbons. n=a number from 2-100.