• 专利标题:   Synthesizing helical carbon nanostructures by introducing molten carbonate electrolyte into inter-electrode space, introducing carbon input into inter-electrode space, applying current across electrodes, and collecting product.
  • 专利号:   WO2021087165-A1, IN202247020756-A, CA3156243-A1, CN114630926-A, EP4051627-A1, US2022388847-A1, BR112022007194-A2, CA3156243-C
  • 发明人:   LICHT S, LICHT G
  • 专利权人:   C2CNT LLC, C2CNT LLC, C2CNT LLC
  • 国际专利分类:   B82Y040/00, C25B001/00, H01M008/14, C25B001/04, C01B032/15, C25B001/135, C01B032/16, B82Y030/00, C25B009/09
  • 专利详细信息:   WO2021087165-A1 06 May 2021 B82Y-040/00 202141 Pages: 36 English
  • 申请详细信息:   WO2021087165-A1 WOUS058046 29 Oct 2020
  • 优先权号:   US927389P, US17760690, BR11007194, CN80073487, CA3156243

▎ 摘  要

NOVELTY - Synthesizing helical carbon nanostructures (HCNS) involves: (a) aligning an anode spaced from a cathode for defining an inter-electrode space; (b) introducing a molten carbonate electrolyte into the inter-electrode space; (c) introducing a carbon input into the inter-electrode space; (d) applying a current across the electrodes; and (e) collecting a product that comprises the HCNS from the electrode. USE - The method is useful for synthesizing HCNS (claimed). ADVANTAGE - Conveniently, carbon nanomaterials produced from a molten carbonate by electrolysis can be produced with a relatively low carbon footprint and even a negative carbon footprint, because carbon dioxide (CO2) is consumed as a reactant, and at relatively low cost, as compared to carbon nanomaterials produced by other conventional techniques such as chemical vapor deposition (CVD) synthesis, flame synthesis, or plasma synthesis. The predominance of HCNSs may be produced by molten carbon electrolytic splitting under growth conditions that: (1) maximize torsional stress, such as those that may occur during rapid, nucleated growth; (2) enhance defects that cause formation of heptagonal, rather than the conventional pentagonal building blocks of graphene cylindrical walls; (3) uniformly control those enhanced defects to repeatedly induce a uniform spiral conformation; and (4) employ combinations of (1), (2) and (3). DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for: (1) HCNS synthesized by a molten carbonate electrolysis method; and (2) a system for making HCNS, comprising: (a) an anode; (b) a cathode; (c) an inter-electrode space that is defined between the anode and the cathode; (d) a source of current for applying a current density is greater than or equal to 0.2 A/cm2 across the electrodes; (e) a source of heat for regulating the inter-electrode space at greater than or equal to 725 degrees C; and (f) a source of carbon for introducing a carbon input into the inter-electrode space.