• 专利标题:   Composite electrochromic film comprises indium tin oxide conductive glass or fluorine-doped tin oxide conductive glass as substrate coated with composite film comprising cobalt (II, III)/reduced graphene oxide modified in nickel oxide film.
  • 专利号:   CN108117277-A
  • 发明人:   WEI A, WANG R, WEI W
  • 专利权人:   UNIV NANJING POSTS TELECOM
  • 国际专利分类:   C03C017/34
  • 专利详细信息:   CN108117277-A 05 Jun 2018 C03C-017/34 201844 Pages: 8 Chinese
  • 申请详细信息:   CN108117277-A CN11446485 27 Dec 2017
  • 优先权号:   CN11446485

▎ 摘  要

NOVELTY - A composite electrochromic film comprises indium tin oxide (ITO) conductive glass or fluorine-doped tin oxide (FTO) conductive glass as substrate coated with composite film on surface. The composite film is a ternary composite material comprising cobalt (II, III)/reduced graphene oxide (Co3O4/rGO) uniformly modified in nickel oxide (NiO) film with loose porous shape and nano-level aperture. The Co3O4 has nano-level particle diameter. USE - Composite electrochromic film. ADVANTAGE - The film improves coloring efficiency, cycling stability and electrochromic performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the composite electrochromic film comprising covering polyimide tape on non-conductive surface of substrate, adding hexahydrated nickel sulfate and potassium peroxydisulfate into deionized water to prepare mixed liquid, vertically suspending substrate in mixed liquid, magnetically stirring, adding 25-28 wt.% ammonia, reacting at 20-50 degrees C for 20-30 minutes, taking out substrate, torning polyimide tape, washing using deionized water, drying, calcining in muffle furnace at 250-350 degrees C for 2 hours, naturally cooling to room temperature to obtain NiO film surface coated substrate, adding cobalt acetate tetrahydrate to anhydrous ethanol, fully stirring, adding 25-28 wt.% ammonia, reacting to obtain solution, dissolving graphene oxide powder into deionized water, ultrasonically processing, adding to solution, transferring to hydrothermal kettle, reacting at 120-150 degrees C for 7-9 hours, filtering, washing, adding deionized water to obtain Co3O4/rGO suspension, soaking substrate, modifying, washing with deionized water, repeating operation and drying.