• 专利标题:   Electrochemical process for synthesis of graphene in the form of ribbons, layers and urchins from carbon nanotubes, by dispersing carbon nanotubes in ethanol, oxidizing nanotubes in conducting solution by applying a positive potential.
  • 专利号:   WO2012035551-A1, US2013175182-A1, EP2616392-A1, IN201002176-I1, KR2013108580-A, CN103237756-A, US8834701-B2, EP2616392-B1, ES2542618-T3, CN103237756-B, IN292438-B, KR1920092-B1
  • 发明人:   SHINDE D B, PILLAI V K, PILLAI V, SHINDE D
  • 专利权人:   COUNCIL SCI IND RES INDIA, COUNCIL SCI IND RES INDIA, COUNCIL SCI IND RES INDIA, COUNCIL SCI IND RES INDIA, COUNCIL SCI IND RES INDIA, COUNCIL SCI IND RES INDIA
  • 国际专利分类:   C01B031/04, C01B000/00, B01J019/08, C01B031/02, B82Y030/00, B82Y040/00, C25B001/00
  • 专利详细信息:   WO2012035551-A1 22 Mar 2012 C01B-031/04 201224 Pages: 22 English
  • 申请详细信息:   WO2012035551-A1 WOIN000623 13 Sep 2011
  • 优先权号:   INDE02176, WOIN000623, KR709328, CN80054826

▎ 摘  要

NOVELTY - The electrochemical process comprises dispersing carbon nanotubes (CNTs) in ethanol by sonication followed by deposition onto a polar/non polar conducting substrate by dip coating, spin coating/brush coating, oxidizing CNTs in conducting solution by applying a positive potential for period of 4-12 hrs to obtain CNT oxide, and reducing CNT oxide by applying negative potential for period of 4-12 hrs to obtain graphene with a yield of 6-7%. The CNTs consist of single walled, double walled and multi walled CNTs, where positive and negative potentials are 0.5-0.8V and -0.5 to -0.7 V respectively. USE - The electrochemical process for synthesis of graphene in the form of ribbons, layers, scrolls, flowers and urchins (claimed) from carbon nanotubes. ADVANTAGE - The electrochemical process ensures synthesis of graphene with improved room temperature quantum hall effect, long range ballistic transport, high quality, conductivity and mobility, increased yield, less defects and more uniform layer thickness.