• 专利标题:   Graphene-metal composite fiber prepared by e.g. using wet spinning method, heating and reducing, fixing pure graphene fiber to cathode electrode of the plating groove for plating, removing fiber and washing with deionized water.
  • 专利号:   CN106637935-A, CN106637935-B
  • 发明人:   GAO C, FANG B
  • 专利权人:   UNIV ZHEJIANG, UNIV ZHEJIANG
  • 国际专利分类:   C25D003/48, C25D007/06, D06M101/40, D06M011/83
  • 专利详细信息:   CN106637935-A 10 May 2017 D06M-011/83 201735 Pages: 7 Chinese
  • 申请详细信息:   CN106637935-A CN11219103 26 Dec 2016
  • 优先权号:   CN11219103

▎ 摘  要

NOVELTY - Graphene-metal composite fiber is claimed. The composite fibers are made of pure graphene fibers and gold layer composition of coated pure graphene fibers, surface of pure graphene fiber having pleats, and embedding gold layer with pleat to elongate structure. USE - The method is useful for preparing graphene-metal composite fiber (claimed). ADVANTAGE - The method has stable fiber structure and improves electrical property of material, and can bends hundred times but conductivity does not change. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing graphene-metal composite fiber comprising (i) preparing graphene oxide fiber using wet spinning method, where diameter is 1-50 m, (ii) then placing graphene oxide fiber in high-temperature furnace, heating and reducing to obtain pure graphene fiber, and (iii) fixing pure graphene fiber to anode electrode of the plating groove for plating, where anode electrode of plating tank is graphite rod, applying direct current voltage of 0.1-20 V, plating in plating solution for 2-120 seconds, removing fiber, washing surface of fiber with deionized water, drying in an oven under vacuum to obtain graphene-gold composite fiber, where the composition of plating solution composed of gold trichloride having concentration of 25-45 g/l, 60 wt.% hydrochloric acid having volume concentration of 1-8 ml/l, sodium sulfite having concentration of 80-150 g/l, and ammonium citrate having concentration of 60-100 g/l.