• 专利标题:   Anode used in lithium battery, comprises ternary lithium-iron phosphate, N-methyl-2-pyrrolidone and additive containing polyvinylidene fluoride, KS-6 graphite and multilayer graphene including several layers of flaky graphene and diamond.
  • 专利号:   CN107482167-A
  • 发明人:   XU H
  • 专利权人:   KUNSHAN ZHENGGUO NEW ENERGY POWER BATTER
  • 国际专利分类:   H01M010/0525, H01M010/42, H01M010/613, H01M010/653, H01M010/654, H01M004/131, H01M004/136, H01M004/1391, H01M004/1397, H01M004/36, H01M004/505, H01M004/525, H01M004/58, H01M004/62
  • 专利详细信息:   CN107482167-A 15 Dec 2017 H01M-004/131 201809 Pages: 7 Chinese
  • 申请详细信息:   CN107482167-A CN10600462 21 Jul 2017
  • 优先权号:   CN10600462

▎ 摘  要

NOVELTY - An anode comprises 40-44 wt.% ternary lithium-iron phosphate, 46-50 wt.% N-methyl-2-pyrrolidone solvent and an additive comprising 2-3 wt.% polyvinylidene fluoride, 1-2 wt.% SP, 1-2 wt.% KS-6 graphite and 5-8 wt.% multilayer graphene. The multilayered graphene includes several layers of flaky graphene and diamond. The weight ratio of multilayered graphene and diamond is (4-6):1. The multilayered graphene comprises 6-8 layers of graphene. The thickness of each layer of the multilayered graphene is 0.3-1.0 nm. The diamond is spherical carbon having particle diameter of 0.7-1.6 nm. USE - Anode is used in lithium battery. ADVANTAGE - The multilayer graphene in the anode increases thermal conductivity and electroconductivity of the lithium battery, and effectively reduces internal resistance of the battery. When the battery is exposed to the high-temperature environment, the heat can be transmitted to the battery shell to dissipate outwardly, such that internal temperature of the battery is decreased and stability of the battery is maintained. The lithium battery provided with the anode is safe, and can adapt to the high temperature of 75 degrees C, and long service life. DETAILED DESCRIPTION - An anode comprises 40-44 wt.% ternary lithium-iron phosphate as main ingredient, 46-50 wt.% N-methyl-2-pyrrolidone solvent and an additive comprising 2-3 wt.% polyvinylidene fluoride, 1-2 wt.% SP, 1-2 wt.% KS-6 graphite and 5-8 wt.% multilayer graphene. The multilayered graphene includes several layers of flaky graphene and diamond located between two adjacent layers of the multilayered flaky graphene. The weight ratio of multilayered graphene and diamond is (4-6):1. The multilayered graphene comprises 6-8 layers of graphene. The thickness of each layer of the multilayered graphene is 0.3-1.0 nm. The spacing between the two adjacent layers of the multilayered graphene is 0.1-0.5 nm. The diamond is spherical carbon having particle diameter of 0.7-1.6 nm.