• 专利标题:   Annealing sapphire substrate used for transfer of graphene, by introducing hydrogen, argon and methane gases into copper foil, soaking in ferric pernitrate and acetone, and rinsing with ethanol and deionized water, passing into argon gas.
  • 专利号:   CN102931078-A, CN102931078-B
  • 发明人:   WANG D, CHAI Z, NING J, ZHANG J, HAN D, HAO Y, YAN Y
  • 专利权人:   UNIV XIDIAN
  • 国际专利分类:   C23C016/26, C23C016/56, H01L021/324
  • 专利详细信息:   CN102931078-A 13 Feb 2013 H01L-021/324 201362 Pages: 7 Chinese
  • 申请详细信息:   CN102931078-A CN10408221 22 Oct 2012
  • 优先权号:   CN10408221

▎ 摘  要

NOVELTY - Annealing of sapphire substrate comprises putting copper foil into reaction chamber, and introducing hydrogen gas (H2); introducing argon (Ar) and methane gas into reaction chamber; soaking into 0.05-0.15 g/ml ferric pernitrate (Fe(NO4)3) solution for 30-60 minutes using sapphire substrate salvaged; soaking in acetone for 24 hours to completely remove residual polymethyl methacrylate (PMMA); rinsing with ethanol and deionized water, and drying high-purity nitrogen gas; evacuating the reaction chamber, passing into Ar gas; and introducing mixed gas of Ar and H2. USE - Method for annealing sapphire substrate used for transfer of graphene (claimed). ADVANTAGE - The method has low-temperature annealing with hydrogen gas atmosphere to remove the water molecules adsorbed on the surface of graphene and other impurities; repairing substrate transfer of graphene defects generated, further removing unremoved impurities, and improving contact of substrate and graphene (claimed); optimizing adhering of the electrical properties of the graphene on the sapphire substrate, and ultimately enable clean transfer surface of the graphene, and fewer defects.