• 专利标题:   Preparation of polyimide film with low dielectric and high heat conductivity by preparing polyamic acid resin solution, and adding silver salt dispersion liquid and heat conducting filler dispersing slurry in polyamic acid resin solution.
  • 专利号:   CN113234244-A
  • 发明人:   ZHU L, WANG Z, WANG Y, REN X
  • 专利权人:   GUILIN ELECTRICAL EQUIP SCI RES INST
  • 国际专利分类:   C08J005/18, C08K003/04, C08K003/08, C08K003/22, C08K003/28, C08K003/38, C08L079/08
  • 专利详细信息:   CN113234244-A 10 Aug 2021 C08J-005/18 202185 Pages: 17 Chinese
  • 申请详细信息:   CN113234244-A CN10609229 01 Jun 2021
  • 优先权号:   CN10609229

▎ 摘  要

NOVELTY - Preparation of polyimide film with low dielectric and high heat conductivity comprises preparing polyamic acid resin solution; and adding silver salt dispersion liquid and heat conducting filler dispersing slurry in the polyamic acid resin solution, uniformly mixing, and carrying out constant-temperature thermal decomposition, imidization and sizing treatment on the obtained mixed resin solution after casting to form a film so as to obtain a low-dielectric high-heat-conducting polyimide film. The silver salt dispersion liquid is silver salt dispersed in a polar aprotic solvent to form a solution, where silver salt is selected from silver nitrate, silver carbonate and/or silver oxalate, the adding amount of silver salt dispersion liquid is 0.1-10 wt.% of the solid content of the polyamic acid resin solution, and the heat-conducting filler dispersing slurry is formed by dispersing heat-conducting filler in polar aprotic solvent. USE - The method is for preparation of polyimide film with low dielectric and high heat conductivity (claimed). ADVANTAGE - The method provides film with low dielectric property and high heat conductivity while adding the heat-conducting filler in a small amount. DETAILED DESCRIPTION - Preparation of polyimide film with low dielectric and high heat conductivity comprises preparing polyamic acid resin solution; and adding silver salt dispersion liquid and heat conducting filler dispersing slurry in the polyamic acid resin solution, uniformly mixing, and carrying out constant-temperature thermal decomposition, imidization and sizing treatment on the obtained mixed resin solution after casting to form a film so as to obtain a low-dielectric high-heat-conducting polyimide film. The silver salt dispersion liquid is silver salt dispersed in a polar aprotic solvent to form a solution, where silver salt is selected from silver nitrate, silver carbonate and/or silver oxalate, the adding amount of silver salt dispersion liquid is 0.1-10 wt.% of the solid content of the polyamic acid resin solution, the heat-conducting filler dispersing slurry is formed by dispersing heat-conducting filler in polar aprotic solvent, the adding amount of heat-conducting filler dispersing slurry is 0.8-1.2 times the adding amount of silver salt, and the constant temperature thermal decomposition treatment is conducted at 190-220 degrees C for greater than or equal to 5 minutes. An INDEPENDENT CLAIM is included for polyimide film with low dielectric and high heat conductivity.