• 专利标题:   Preparing 5-hydroxymethyl furoic acid, comprises contacting aqueous solution of 5-hydroxymethyl furfural with catalyst under air and/or oxygen conditions, and carrying out catalytic oxidation reaction.
  • 专利号:   CN112778248-A, CN112778248-B
  • 发明人:   ZHENG L, SUN Q, DU Z, ZONG B
  • 专利权人:   CHINA PETROLEUM CHEM CORP, SINOPEC RES INST PETROLEUM PROCESSING, CHINA PETROLEUM CHEM CORP RES INST
  • 国际专利分类:   B01J023/42, B01J023/44, B01J023/46, C07D307/68
  • 专利详细信息:   CN112778248-A 11 May 2021 C07D-307/68 202156 Pages: 12 Chinese
  • 申请详细信息:   CN112778248-A CN11069951 05 Nov 2019
  • 优先权号:   CN11069951

▎ 摘  要

NOVELTY - Preparing 5-hydroxymethyl furoic acid, comprises contacting aqueous solution of 5-hydroxymethyl furfural with catalyst under air and/or oxygen conditions, and carrying out catalytic oxidation reaction to prepare 5-hydroxymethyl furoic acid, where the catalyst is obtained by mixing front carrier and basic nitrogen-containing compound in solvent, heating and stirring in a water bath, and performing alkali treatment, drying and calcining the front carrier after the alkali treatment to obtain carrier, and loading the active component on the carrier; where the active component is ruthenium, palladium, platinum, rhodium, iridium and/or osmium; and the front carrier is activated carbon, graphite, fullerene and/or graphene oxide. USE - The method is useful for preparing 5-hydroxymethyl furoic acid. ADVANTAGE - The method: has high product selectivity, simple operation, and mild reaction condition; and is environmentally-friendly, and suitable for industrial production.