• 专利标题:   Graphene/polyimide composite carbon film has specified range of thickness, porosity and thermal conductivity and is prepared by coating aqueous graphene oxide solution on surface of polyimide film, drying, heating and hot pressing.
  • 专利号:   CN107090275-A, WO2018219000-A1
  • 发明人:   GAO C, GUO Y
  • 专利权人:   HANGZHOU GAOXI TECHNOLOGY CO LTD, HANGZHOU GAOXI TECHNOLOGY CO LTD
  • 国际专利分类:   C09K005/14
  • 专利详细信息:   CN107090275-A 25 Aug 2017 C09K-005/14 201770 Pages: 5 Chinese
  • 申请详细信息:   CN107090275-A CN10391019 27 May 2017
  • 优先权号:   CN10391019, CN10398136

▎ 摘  要

NOVELTY - A graphene/polyimide composite carbon film has a thickness of greater than 100 mu m, a porosity of 10-40% and a thermal conductivity of 1000-1700 W/mK. The carbon film has no stratification phenomenon. A distance between any two adjacent graphene layers is less than 20 nm. USE - Graphene/polyimide composite carbon film (claimed). ADVANTAGE - The graphene/polyimide composite carbon film has high thermal conductivity. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the method for the production of the composite carbon film, which involves formulating graphene oxide having an average size of more than 50 mu m into 1-10 mg/ml an aqueous graphene oxide solution, uniformly coating the aqueous graphene oxide solution on a surface of a polyimide film, adhering the polyimide films together in the thickness direction, placing the adhered graphene oxide/polyimide composite film in a drying oven, drying the film at less than 40 degrees C, placing the dried graphene oxide/polyimide composite film in a carbonization furnace, heating at a temperature of 1000 degrees C, a pressure of 20-200 MPa and a heating rate of 0.1-5 degrees C/minute for 1 hour under argon atmosphere, subjecting the graphene oxide/polyimide composite carbon film to hot pressing at a temperature of 2500-3000 degrees C, a pressure of 60 MPa and a heating rate of 1-20 degrees C/minute for 0.5-8 hours under inert gas atmosphere and cooling to obtain the graphene oxide/polyimide composite carbon film.