• 专利标题:   Reduction preparation of nano-silver-particle-loaded graphene oxide catalyst used for amination of p-nitrophenol, involves centrifuging viscous polydopamine using graphene oxide, adding silver nitrate, stirring, and freeze-drying.
  • 专利号:   CN108927150-A
  • 发明人:   HUANG A, QIAN Y
  • 专利权人:   UNIV EAST CHINA NORMAL
  • 国际专利分类:   B01J023/50, B01J035/02, C07C213/02, C07C215/76
  • 专利详细信息:   CN108927150-A 04 Dec 2018 B01J-023/50 201914 Pages: 10 Chinese
  • 申请详细信息:   CN108927150-A CN10500340 23 May 2018
  • 优先权号:   CN10500340

▎ 摘  要

NOVELTY - Reduction preparation of nano-silver-particle-loaded graphene oxide catalyst, involves adding freeze-dried graphene oxide powder to deionized water, ultrasonically dispersing for 30-50 minutes to obtain 0.5-2 mg/mL graphene oxide solution, adding tris(hydroxymethyl)aminomethane buffer to the graphene oxide solution, adjusting the pH to 8.5, adding 1-3 mg/mL dopamine hydrochloride, stirring at room temperature for 19-22 hours, while dopamine polymerization cyclization slowly occurs under the action of oxygen in air to obtain a viscous polydopamine, centrifuging, washing, removing chloride ions, adding silver nitrate solid, stirring at room temperature for 23-26 hours, washing, removing unreacted silver nitrate, and freeze-drying. The loading amount of nano silver particles is 10-50%. USE - Reduction preparation of nano-silver-particle-loaded graphene oxide catalyst used for amination of p-nitrophenol (claimed). DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for use of the catalyst for amination of p-nitrophenol under normal pressure and temperature for 10-30 minutes, using sodium borohydride, at a conversion efficiency of 58.6-99.5%.