• 专利标题:   Preparation of graphene for energy storage materials, involves flash thermal treatment of graphite oxide to produce exfoliation, cooling, and heating at temperature higher than flash thermal treatment temperature at preset rate.
  • 专利号:   WO2016042099-A1, EP3148933-A1, KR2017059999-A, CN107074553-A, US2017260055-A1, JP2017533162-W, EP3148933-B1, ES2675232-T3
  • 发明人:   PAEZ DUENAS A, GARCIA SAN LUIS J, ALVAREZ RODRIGUEZ P, GRANDA M, BLANCO RODRIGUEZ C, SANTAMARIA RAMIREZ R, BLANCO P, FERNANDEZ L, MENENDEZ LOPEZ R M, CALLE GOMEZ F, PAEZ D A, GARCIA S L J, ALVAREZ R P, BLANCO R C, SANTAMARIA R R, MENENDEZ L R M, CALLE G F, CALLE G M F, DUEAAS A P, RODRAGUEZ C B, SAN LUIS J G, SANTAMARAA R R, MENA N L P R M
  • 专利权人:   REPSOL SA, REPSOL INC
  • 国际专利分类:   C01B031/04, C01B032/182, C01B032/192, C01B031/02
  • 专利详细信息:   WO2016042099-A1 24 Mar 2016 201623 Pages: 28 English
  • 申请详细信息:   WO2016042099-A1 WOEP071367 17 Sep 2015
  • 优先权号:   EP382352

▎ 摘  要

NOVELTY - Preparation of graphene, involves flash thermal treatment of graphite oxide under inert atmosphere at 700 degrees C or less to produce exfoliation, cooling the material to less than 90 degrees C, and heating the resulting material under inert atmosphere at a temperature higher than the flash thermal treatment temperature, at a heating rate between 1 degrees C/minute and 15 degrees C/minute. USE - Preparation of graphene (claimed) used for preparing mixtures with spinels and other fillers to prepare improved and more homogeneous materials used for storing energy (e.g. batteries, supercondensers). ADVANTAGE - The method enables preparation of graphene having excellent physicochemical properties, controlled residual oxygenated functional group portion (direct consequence of the final temperature selected in the treatment), controlled surface area, which relates also with its volume, high capacity to be dispersed in solvents, and excellent processability. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic view of the reactor used for flash thermal treatment of graphite oxide. Inlet (1) Preheated volume (2) Oven (3) Heater (5) Inlet valve (8)