• 专利标题:   Preparation of magnesium-doped silicon oxide composite negative electrode material involves sintering silicon oxide fine powder and metal magnesium powder, dispersing in prepared silica sol composite material, sintering, and etching.
  • 专利号:   CN116169265-A
  • 发明人:   ZHANG J, MA T, JIANG Q
  • 专利权人:   WANHUA CHEM YANTAI BATTERY MATERIAL TECH
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/48, H01M004/62
  • 专利详细信息:   CN116169265-A 26 May 2023 H01M-004/36 202352 Chinese
  • 申请详细信息:   CN116169265-A CN10116015 15 Feb 2023
  • 优先权号:   CN10116015

▎ 摘  要

NOVELTY - Preparation of magnesium-doped silicon oxide composite negative electrode material involves (s1) weighing silicon oxide fine powder and metal magnesium powder, mixing uniformly, sintering at high temperature, and crushing the sintered material to obtain a precursor (A), (s2) dispersing a non-amorphous carbon material in a silica sol to obtain a silica sol composite material, (s3) uniformly dispersing the precursor (A) in the silica sol composite material, spray drying, sintering, and crushing to obtain a precursor (B) having a core-shell structure, and (s4) using hydrofluoric acid solution to etch the precursor (B), filtering, washing to neutral, and drying. USE - Preparation of magnesium-doped silicon oxide composite negative electrode material (claimed). ADVANTAGE - The method is simple and economical, and provides negative electrode material having excellent electrical performance, stability and multi-stage volume buffer performance, which effectively alleviates the volume expansion of silicon oxide during charging and discharging. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for magnesium-doped silicon oxide composite negative electrode material, which comprises an inner core and an outer shell. The inner core is a magnesium-doped silicon oxide material, and the outer shell is a non-amorphous carbon material conductive layer.