• 专利标题:   Metal/organic carbon nanocomposite used for lithium-sulfur battery comprises graphene and sulfur as active ingredients and complex in which a first zeolitic imidazolate framework (ZIF) and second ZIF exist in a core-shell form.
  • 专利号:   KR2021012480-A, KR2221184-B1
  • 发明人:   KIM S, SONG W
  • 专利权人:   UNIV PUSAN NAT IND COOP FOUND
  • 国际专利分类:   C01B017/02, C01B032/182, C07F015/06, C07F003/06, H01M010/052, H01M010/0568, H01M004/36, H01M004/38, H01M004/62
  • 专利详细信息:   KR2021012480-A 03 Feb 2021 H01M-004/36 202115 Pages: 16
  • 申请详细信息:   KR2021012480-A KR090286 25 Jul 2019
  • 优先权号:   KR090286

▎ 摘  要

NOVELTY - Metal/organic carbon nanocomposite comprises graphene and sulfur as active ingredients and complex in which a first zeolitic imidazolate framework (ZIF) and second ZIF exist in a core-shell form. USE - Metal/organic carbon nanocomposite used for lithium-sulfur battery (claimed). ADVANTAGE - The metal/organic carbon nanocomposite has high charge/discharge capacity by each containing cobalt and zinc having similar crystal forms, and exhibit excellent cycle stability and rate-limiting characteristics. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for producing a metal/organic carbon nanocomposite which involves (S1) preparing a first ZIF by reacting cobalt and organic ligand, and preparing a first ZIF/graphene oxide by mixing with graphene oxide; (S2) preparing a second ZIF by reacting zinc and organic ligand, and mixing the graphene oxide/first ZIF to prepare a first ZIF/second ZIF/graphene oxide; (S3) preparing the first ZIF/second ZIF/graphene by heat-treating the first ZIF/second ZIF/graphene oxide; and (S4) preparing a metal/organic carbon nanocomposite composed of first ZIF/second ZIF/graphene/sulfur by adding a sulfur material.