• 专利标题:   Preparation of doped graphene carbon nanofibers for e.g. hydrogen storage, involves electrostatically spinning polymerized acrylonitrile, and doped graphene using ammonium persulfate, drafting, pre-oxidizing, carbonizing, and graphitizing.
  • 专利号:   CN113174658-A
  • 发明人:   ZHU B, ZHANG Y, QIAO K, YU J
  • 专利权人:   UNIV SHANDONG
  • 国际专利分类:   B82Y030/00, B82Y040/00, D01F009/22, H01M004/96
  • 专利详细信息:   CN113174658-A 27 Jul 2021 D01F-009/22 202172 Pages: 9 Chinese
  • 申请详细信息:   CN113174658-A CN10373531 07 Apr 2021
  • 优先权号:   CN10373531

▎ 摘  要

NOVELTY - Preparation of doped graphene carbon nanofibers involves preparing a spinning solution by mixing acrylonitrile and doped graphene material with water, polymerizing using ammonium persulfate or ammonium persulfate-ammonium persulfate composite as initiator, and dissolving the product in an organic solution, electrostatically spinning the spinning solution to obtain nanofiber felt, and subjecting the obtained nanofiber felt to thermal drafting, pre-oxidizing, carbonizing and graphitizing. USE - Preparation of doped graphene carbon nanofibers used as and/or for preparation of hydrogen storage, high capacity electrode, and high-performance composite material (all claimed). ADVANTAGE - The method enables simple, highly productive, and efficient preparation of doped graphene carbon nanofibers having high regularity, improved mechanical properties, and thermal conductivity. The nano-size of the fibers avoids generation of skin-core structure and the fiber includes graphene that accelerates the dissolution of the polymeric materials.