• 专利标题:   Zinc oxide-based heterojunction photo-catalytic composite material for efficient photo-catalytic treatment of neonicotinoid pesticide pollutant, comprises a single layer reduced graphene oxide as the elementary material.
  • 专利号:   CN114130397-A, CN114130397-B
  • 发明人:   ZHONG D, LENG L, LI Z, YAO T, YANG L
  • 专利权人:   HARBIN INST TECHNOLOGY SHENZHEN GRADUATE
  • 国际专利分类:   B01J023/80, C02F001/30, C02F101/34, C02F101/38, C02F103/34
  • 专利详细信息:   CN114130397-A 04 Mar 2022 B01J-023/80 202246 Chinese
  • 申请详细信息:   CN114130397-A CN11428842 26 Nov 2021
  • 优先权号:   CN11428842

▎ 摘  要

NOVELTY - Zinc oxide-based heterojunction photo-catalytic composite material comprises a single layer reduced graphene oxide (rGO) as the elementary material, where the elementary material is grafted with titanium oxide nano particles, zinc oxide nano-particle and ferric oxide nanoparticle zinc oxide @titanium oxide-reduced graphene oxide/ferric oxide nano material, the x is 0.05-0.45. USE - Zinc oxide-based heterojunction photo-catalytic composite material used for efficient photo-catalytic treatment of neonicotinoid pesticide pollutant (claimed). ADVANTAGE - The zinc oxide-based heterojunction photo-catalytic composite material has visible light capable of absorbing full visible spectrum, convenient recycling and reusing, which is suitable for efficient photo-catalytic treatment of neonicotinoid pesticide pollutant. DETAILED DESCRIPTION - Zinc oxide-based heterojunction photo-catalytic composite material comprises a single layer reduced graphene oxide (rGO) as the elementary material, where the elementary material is grafted with titanium oxide (TiO2-x) nano particles, zinc oxide(ZnO1-x) nanoparticle and ferric oxide nanoparticle zinc oxide @titanium oxide-reduced graphene oxide/ferric oxide nano material (ZnO 1-x@TiO2-x-rGo/Fe3O4), the x is 0.05-0.45. An INDEPENDENT CLAIM is included for a method for preparing a zinc oxide-based heterojunction photo-catalytic composite material, involving: a. preparing titanium oxide sol; b. preparing titanium oxide-reduced graphene oxide/ferric oxide suspension; c. adding the zinc acetate dissolved in the distilled water into the titanium oxide-reduced graphene oxide/ferric oxide suspension; d. using sodium hydroxide solution to adjust the pH value to 12, performing the first hydrothermal reaction; and e. performing the first post-treatment to the reaction system after the first hydrothermal reaction to obtain product.