• 专利标题:   Manufacture of graphene/ceramic laminate involves alternately stacking graphene oxide-containing ceramic components each having different graphene oxide content, hot-pressing and sintering.
  • 专利号:   CN105218103-A, CN105218103-B
  • 发明人:   HAN J, HAN W, HU P, ZHANG X, CHENG Y, AN Y
  • 专利权人:   HARBIN INST TECHNOLOGY, HARBIN INST TECHNOLOGY
  • 国际专利分类:   C04B035/58, C04B035/622, C04B035/81, C01B003/04
  • 专利详细信息:   CN105218103-A 06 Jan 2016 C04B-035/58 201642 Pages: 13 English
  • 申请详细信息:   CN105218103-A CN10701406 26 Oct 2015
  • 优先权号:   CN10701406

▎ 摘  要

NOVELTY - Two or more graphene oxide-containing ceramic components (A)-(D) each having different contents of graphene oxide, are alternately stacked, hot-pressed in vacuum, inert or argon atmosphere, sintered at 1800-2000 degrees C in the sintering pressure of 30-50 MPa for 30-60 minutes to obtain graphene/ceramic laminate. USE - Manufacture of graphene/ceramic laminate (claimed). ADVANTAGE - The method efficiently and economically provides graphene/ceramic laminate having room-temperature breaking toughness of 8-10 MPa and three-point bend strength of 400-600 MPa, by simple method. DETAILED DESCRIPTION - 40-85 Vol.% zirconium diboride powder and 10-25 vol.% silicon carbide material as matrix material, 3-35 vol.% graphene oxide as reinforcing agent, and ethanol as solvent are subjected to high-speed planetary ball mill, and wet-mixed to obtain slurry. The obtained slurry is cast on polytetrafluoroethylene substrate molding, to obtain graphene oxide-containing layered ceramic component (A). 40-85 Vol.% zirconium diboride powder and 10-25 vol.% silicon carbide material as matrix material, 3-35 vol.% graphene oxide as reinforcing agent, and ethanol as solvent are subjected to high-speed planetary ball mill, and wet-mixed to obtain slurry. The obtained slurry is cast on polytetrafluoroethylene substrate molding, to obtain graphene oxide-containing layered ceramic component (B). 40-85 vol.% Zirconium diboride powder and silicon carbide material as matrix material, 3-35 vol.% graphene oxide as reinforcing agent, and ethanol as solvent are subjected to high-speed planetary ball mill, and wet-mixed to obtain slurry. The obtained slurry is cast on polytetrafluoroethylene substrate molding, to obtain graphene oxide-containing layered ceramic component (C). 40-85 Vol.% Zirconium diboride powder and 10-25 vol.% silicon carbide material as matrix material, 3-35 vol.% graphene oxide as reinforcing agent, and ethanol as solvent are subjected to high-speed planetary ball mill, and wet-mixed to obtain slurry. The obtained slurry is cast on polytetrafluoroethylene substrate molding, to obtain graphene oxide-containing layered ceramic component (D). The contents of graphene oxide during formation of components (A)-(D) are not the same. Two or more components (A)-(D) are alternately stacked, hot-pressing in vacuum, inert or argon atmosphere, sintered at 1800-2000 degrees C in the sintering pressure of 30-50 MPa for 30-60 minutes to obtain graphene/ceramic laminate.