• 专利标题:   Chemical-bonding preparation of net-shaped three-dimensional graphene, involves activating polyfunctional compound and graphene oxide, forming chemical bond between compound and oxygen, and hydrothermally reacting with graphite oxide.
  • 专利号:   CN103738945-A, CN103738945-B
  • 发明人:   FAN T, LIU Y, MIN Y, SONG J, TONG S, YANG W
  • 专利权人:   NANJING XINYUE MATERIAL TECHNOLOGY CO, YANCHENG ZENGCAI TECHNOLOGY CO LTD
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN103738945-A 23 Apr 2014 C01B-031/04 201442 Pages: 8 Chinese
  • 申请详细信息:   CN103738945-A CN10564176 14 Nov 2013
  • 优先权号:   CN10564176

▎ 摘  要

NOVELTY - Graphite powder is reacted with potassium permanganate/sulfuric acid to obtain a light yellow transparent solution. The solution is dried to obtain a sheet of graphite oxide. A polyfunctional compound and graphene oxide are dispersed in dry dimethylformamide solution and activator is added. The polyfunctional compound and oxygen radicals form a chemical bond by activation, to obtain polyfunctional grafted graphene oxide sheet. Graphite oxide and graphene oxide are hydrothermally reacted to obtain a three-dimensional network of graphene. USE - Chemical-bonding preparation of controllable net-shaped three-dimensional graphene for use in supercapacitors and seawater desalination. DETAILED DESCRIPTION - Graphite powder is slowly added to potassium permanganate/sulfuric acid under ice bath conditions, and stir-reacted. Hydrogen peroxide is added to remove excess potassium permanganate and obtain a light yellow transparent solution. The solution is dried to obtain a sheet of graphite oxide. A polyfunctional compound and graphene oxide are uniformly dispersed in dry dimethylformamide solution and a small amount of activator is added for activation of graphene oxide. The polyfunctional compound and oxygen radicals form a chemical bond by activation, to obtain polyfunctional grafted graphene oxide sheet. Graphite oxide and graphene oxide are added to a solvent to obtain 1-50 mg/ml solution. The reaction mixture is placed in PTFE reactor and hydrothermally reacted for 10-16 hours, to obtain a three-dimensional network of graphene.