• 专利标题:   Preparation of polyaniline sulfonated graphene composite electrode material used for supercapacitor involves mixing sulfonated polyaniline-graphene composite material and acetylene black, grinding, coating on current collector, and drying.
  • 专利号:   CN106910643-A, CN106910643-B
  • 发明人:   FENG W, ZHANG Q, FENG Y
  • 专利权人:   UNIV TIANJIN, UNIV TIANJIN
  • 国际专利分类:   C08G073/02, C08K003/04, C08K009/04, H01G011/30, H01G011/36, H01G011/48, H01G011/86
  • 专利详细信息:   CN106910643-A 30 Jun 2017 H01G-011/48 201766 Pages: 10 Chinese
  • 申请详细信息:   CN106910643-A CN10097230 02 Dec 2013
  • 优先权号:   CN10097230, CN10636626

▎ 摘  要

NOVELTY - Preparation of polyaniline sulfonated graphene composite electrode material comprises dissolving polyvinylidene fluoride in N-methylpyrrolidone, mixing with sulfonated polyaniline-graphene composite material, acetylene black, and polyvinylidene fluoride at ratio of 80:10-15:10-5, grinding, coating on current collector of stainless steel sheet, and drying to obtain composite electrode material. USE - Method for preparing polyaniline sulfonated graphene composite electrode material (claimed) used for supercapacitor. ADVANTAGE - The method has simple process, is quick and environment-friendly. The composite electrode material has high specific capacitance, excellent rate performance, and good circulation stability. DETAILED DESCRIPTION - Preparation of polyaniline sulfonated graphene composite electrode material comprises dissolving polyvinylidene fluoride in N-methylpyrrolidone, mixing with sulfonated polyaniline-graphene composite material, acetylene black, and polyvinylidene fluoride at ratio of 80:10-15:10-5, grinding, coating on current collector of stainless steel sheet, and drying to obtain composite electrode material. The sulfonated polyaniline-graphene composite material is prepared by dispersing sulfonated graphene in deionized water; adding aniline monomer, ultrasonically dispersing under ice bath condition, slowly adding water soluble ammonium sulfate liquid for 0.5-1 hour, ice bath reacting for 4-6 hours, polymerizing, cleaning, drying, dispersing in aqueous sulfuric acid solution, soaking in sulfuric acid, and filtering.