• 专利标题:   Method for preparing carbon-sulfur composite material for lithium-sulfur battery cathode, involves taking graphene oxide and surfactant, and dissolving carbon source in water followed by mixing, incubating, cooling, filtering and drying.
  • 专利号:   CN104733695-A
  • 发明人:   GU Z, TU J, WANG X, XIA X
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   H01M004/13, H01M004/133, H01M004/139, H01M004/1393
  • 专利详细信息:   CN104733695-A 24 Jun 2015 H01M-004/133 201569 Pages: 10 Chinese
  • 申请详细信息:   CN104733695-A CN10140309 27 Mar 2015
  • 优先权号:   CN10140309

▎ 摘  要

NOVELTY - A carbon-sulfur composite material preparing method involves taking graphene oxide and surfactant, and dissolving carbon source in water, and mixing to obtain a mixture. The mixture is incubated at 170-200 degrees C for 12-18 hours and cooled to obtain a precursor product. The precursor product is filtered, dried and put in a nitrogen or argon protective atmosphere, calcined and cooled to obtain graphene sheet structure microporous carbon support material. The microporous carbon material and sublimed sulfur powder are uniformly mixed, incubation closed and cooled to obtain the finished product. USE - Method for preparing a carbon-sulfur composite material that is utilized for a lithium-sulfur battery cathode (claimed). ADVANTAGE - The composite material can be prepared in a simple, easy and economical manner, provides high charging-discharging specific capacity and excellent cycling performance of the battery, and is suitable for mass production. DETAILED DESCRIPTION - A carbon-sulfur composite material preparing method involves taking graphene oxide and surfactant, and dissolving carbon source in water, and mixing to obtain a mixture. The mixture is incubated at 170-200 degrees C for 12-18 hours and cooled to obtain a precursor product. The precursor product is filtered, dried and put in a nitrogen or argon protective atmosphere at 700-900 degrees C, and calcined for 1-3 hours and cooled to obtain graphene sheet structure microporous carbon support material. The microporous carbon material and sublimed sulfur powder are uniformly mixed in a weight ratio of 1:0.5-3 at 150-170 degrees C and incubation closed for 8-16 hours, and cooled to obtain the finished product.