• 专利标题:   Preparing carbon-coated lithium iron phosphate nano-sheet involves mixing lithium, manganese and phosphorus sources in ethylene glycol and treating obtained with graphene oxide.
  • 专利号:   CN105655561-A, CN105655561-B
  • 发明人:   HE P, MA F, ZHOU H
  • 专利权人:   SUZHOU DISIFU NEW ENERGY TECHNOLOGY CO, SUZHOU DISIFU NEW ENERGY TECHNOLOGY CO
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01M010/0525, H01M004/36, H01M004/58, H01M004/583, H01M004/62
  • 专利详细信息:   CN105655561-A 08 Jun 2016 H01M-004/36 201649 Pages: 8 Chinese
  • 申请详细信息:   CN105655561-A CN10108088 29 Feb 2016
  • 优先权号:   CN10108088

▎ 摘  要

NOVELTY - Preparing carbon-coated lithium iron phosphate nano-sheet involves dissolving lithium source and phosphorus source in ethylene glycol with vigorous stirring to obtain a white dispersion liquid. Manganese source is dissolved in a mixed solvent of water and ethylene glycol, and a reducing agent is added to give a clear solution which is added dropwise to the white dispersion and the mixed dispersion is subjected to hydrothermal treatment to obtain lithium manganese phosphate. The lithium manganese phosphate after grinding is mixed with carbon source. USE - Method for preparing carbon-coated lithium iron phosphate nano-sheet (claimed). ADVANTAGE - The method enables to prepare carbon-coated lithium iron phosphate nano-sheet with electrochemical performance. DETAILED DESCRIPTION - Preparing carbon-coated lithium iron phosphate nano-sheet involves dissolving lithium source and phosphorus source in ethylene glycol with vigorous stirring to obtain a white dispersion liquid. Manganese source is dissolved in a mixed solvent of water and ethylene glycol, and a reducing agent is added to give a clear solution which is added dropwise to the white dispersion and the mixed dispersion is subjected to hydrothermal treatment to obtain lithium manganese phosphate. The lithium manganese phosphate after grinding is mixed with carbon source. The mixture is heated and the powder obtained is dispersed in absolute ethanol. Amine is added to the dispersion which is warmed to 50 degrees C for 5 hours. The resultant is milled and the powder is re-dispersed in ethanol, and heated again to 50 degrees C while adding graphene oxide solution dropwise with vigorous stirring for 2 hours. The product obtained is treated with 50% hydrazine hydrate solution, washed thrice with absolute ethanol and then dried for 10 hours at 60 degrees C to obtain carbon-coated lithium iron phosphate.